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At 1127 K and atm pressure, a gaseous mi...

At 1127 K and atm pressure, a gaseous mixture of CO and `CO_(2)` in equilibrium with solid carbon has `90.55%` CO by mass,
`C_((s))+CO_(2(g))hArr2CO_((g))`
`K_(c)` for this reaction at the above temperature is

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If total mass of the mixture of `CO` and `CO_(2)` is `100 g`, then
`CO=90.55 g` and `CO_(2)=100-90.55=9.45 g`
`:.` Number of moles of `CO=90.55//28=3.234`
Number of moles of `CO_(2)=9.45//44=0.215`
`:. P_(CO)=3.234/(3.234+0.215)xx1 atm =0.938 atm`
`p_(CO_(2))=0.215/(3.234+0.215)xx1 atm =0.062 atm`
`K_(p)=p_(CO)^(2)/p_(CO_(2))=((0.938)^(2))/0.062=14.19`
`Deltan_(g)=2-1 :. K_(p)=K_(c )(RT)` or `K_(c )=K_(p)/(RT)`
`=14.19/(0.0821xx1127)=0.153`
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