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Select the close-packing arrangements in...

Select the close-packing arrangements in the following:
a. … `ABABABA` …, b. … `ABCABCABCA` …
c. … `ABABCBCABC` … , d. … `AC CBCABCABC` …

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To determine the close-packing arrangements from the given options, we will analyze each arrangement step by step. ### Step-by-Step Solution: 1. **Option A: `ABABABA`** - This arrangement alternates between A and B. - When visualized in a 2D layer, it can be represented as: ``` A B A B A B A B A ``` - This structure is a type of close packing known as **CCP (Cubic Close Packing)** or **HCP (Hexagonal Close Packing)**, as it allows for efficient packing of spheres. - **Conclusion**: This is a close-packing arrangement. 2. **Option B: `ABCABCABC`** - This arrangement has three different types of spheres (A, B, and C) repeating in a sequence. - When visualized, it can be represented as: ``` A B C A B C A B C ``` - This arrangement corresponds to **HCP (Hexagonal Close Packing)**, where each layer is offset from the previous one. - **Conclusion**: This is a close-packing arrangement. 3. **Option C: `ABABCBCABC`** - This arrangement is a bit more complex as it mixes A, B, and C in a non-repetitive manner. - Visualizing this arrangement: ``` A B A B C B A B C ``` - This structure can be seen as a combination of CCP and HCP arrangements, allowing for efficient packing. - **Conclusion**: This is a close-packing arrangement. 4. **Option D: `AC CBCABCABC`** - This arrangement does not follow a regular pattern and appears more random. - When visualized, it does not maintain a consistent layer structure: ``` A C C B C A B C A B C ``` - This arrangement does not represent a close packing structure as it lacks the regularity required for efficient packing. - **Conclusion**: This is not a close-packing arrangement. ### Final Answer: The close-packing arrangements are: - **Option A: `ABABABA`** - **Option B: `ABCABCABC`** - **Option C: `ABABCBCABC`** **Option D is not a close-packing arrangement.** ---

To determine the close-packing arrangements from the given options, we will analyze each arrangement step by step. ### Step-by-Step Solution: 1. **Option A: `ABABABA`** - This arrangement alternates between A and B. - When visualized in a 2D layer, it can be represented as: ``` ...
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In HCP or CCP constituent particles occupy 74% of the available space. The remaining space (26%) in between the spheres remains unoccupied and is called interstitial voids or holes. Considering the close packing arrangement, each sphere in the second layer rests on the hollow space of the first layer, touching each other. The void created is called tetrahedral void. If R is the radius of the spheres in the close packed arrangement then, R (radius of tetrahedral void) = 0.225 R In a close packing arrangement, the interstitial void formed by the combination of two triangular voids of the first and second layer is called octahedral coid. Thus, double triangular void is surrounded by six spheres. The centre of these spheres on joining, forms octahedron. If R is the radius of the sphere. in a close packed arrangement then, R (radius of octahedral void = 0.414 R). If the anions (A) form hexagonal close packing and cations (C ) occupy only 2/3rd octahedral voids in it, then the general formula of the compound is