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Consider the structure of CsCl (8: 8 coo...

Consider the structure of `CsCl` (`8: 8` coordination). How many `Cs^(o+)` ions occupy the second nearest neighbour locations of a `Cs^(o+)` ion?
8
24
6
16

A

`8`

B

`24`

C

`6`

D

`16`

Text Solution

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The correct Answer is:
To solve the problem of how many Cs⁺ ions occupy the second nearest neighbor locations of a Cs⁺ ion in the CsCl structure, we can follow these steps: ### Step 1: Understand the Structure of CsCl CsCl crystallizes in a body-centered cubic (BCC) lattice structure. In this structure, each Cs⁺ ion is surrounded by Cl⁻ ions, and vice versa. **Hint:** Visualize the arrangement of ions in the CsCl lattice. Cs⁺ ions are at the corners and the center of the cube. ### Step 2: Identify the Nearest Neighbors In the CsCl structure, each Cs⁺ ion has 8 Cl⁻ ions as its nearest neighbors. This is important because it helps us understand the spatial arrangement of the ions. **Hint:** Remember that nearest neighbors are the ions that are directly adjacent to a given ion. ### Step 3: Determine the Second Nearest Neighbors The second nearest neighbors of a Cs⁺ ion are those ions that are not directly adjacent but are still within the lattice. In the case of the CsCl structure, each Cs⁺ ion has 6 Cs⁺ ions as its second nearest neighbors. **Hint:** Consider the geometry of the cube and how ions are positioned relative to each other. ### Step 4: Conclusion Thus, the number of Cs⁺ ions that occupy the second nearest neighbor locations of a Cs⁺ ion in the CsCl structure is **6**. **Final Answer:** 6

To solve the problem of how many Cs⁺ ions occupy the second nearest neighbor locations of a Cs⁺ ion in the CsCl structure, we can follow these steps: ### Step 1: Understand the Structure of CsCl CsCl crystallizes in a body-centered cubic (BCC) lattice structure. In this structure, each Cs⁺ ion is surrounded by Cl⁻ ions, and vice versa. **Hint:** Visualize the arrangement of ions in the CsCl lattice. Cs⁺ ions are at the corners and the center of the cube. ### Step 2: Identify the Nearest Neighbors ...
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