Home
Class 12
CHEMISTRY
The ratio of the volume of a tetragonal ...

The ratio of the volume of a tetragonal lattice unit cell to that of a hexagonal lattice unit cell is (both having same respective lengths)
a.`(sqrt3)/2abc`
b.`(2)/(3sqrt3)`
c.`(2)/(sqrt(3) (a^(2)c)/(b)`
d.`1`

A

`(sqrt3)/2abc`

B

`(2)/(3sqrt3)`

C

`(2)/(sqrt(3) (a^(2)c)/(b)`

D

`1`

Text Solution

AI Generated Solution

The correct Answer is:
To find the ratio of the volume of a tetragonal lattice unit cell to that of a hexagonal lattice unit cell, we start by calculating the volumes of both unit cells. ### Step 1: Calculate the volume of the hexagonal unit cell The volume \( V_h \) of a hexagonal unit cell is given by the formula: \[ V_h = \frac{3\sqrt{3}}{2} a^2 c \] where \( a \) is the length of the base and \( c \) is the height. ### Step 2: Calculate the volume of the tetragonal unit cell The volume \( V_t \) of a tetragonal unit cell is given by the formula: \[ V_t = a^2 c \] where \( a \) is the length of the sides and \( c \) is the height. ### Step 3: Set up the ratio of the volumes Now we need to find the ratio of the volume of the tetragonal unit cell to that of the hexagonal unit cell: \[ \text{Ratio} = \frac{V_t}{V_h} = \frac{a^2 c}{\frac{3\sqrt{3}}{2} a^2 c} \] ### Step 4: Simplify the ratio In this ratio, \( a^2 \) and \( c \) in the numerator and denominator will cancel out: \[ \text{Ratio} = \frac{1}{\frac{3\sqrt{3}}{2}} = \frac{2}{3\sqrt{3}} \] ### Conclusion Thus, the ratio of the volume of a tetragonal lattice unit cell to that of a hexagonal lattice unit cell is: \[ \frac{2}{3\sqrt{3}} \] ### Final Answer The correct answer is option **b. \( \frac{2}{3\sqrt{3}} \)**. ---

To find the ratio of the volume of a tetragonal lattice unit cell to that of a hexagonal lattice unit cell, we start by calculating the volumes of both unit cells. ### Step 1: Calculate the volume of the hexagonal unit cell The volume \( V_h \) of a hexagonal unit cell is given by the formula: \[ V_h = \frac{3\sqrt{3}}{2} a^2 c \] ...
Promotional Banner

Topper's Solved these Questions

  • SOLID STATE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Assertion-Reasoning)|19 Videos
  • SOLID STATE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Interger)|9 Videos
  • SOLID STATE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Multiple Correct)|39 Videos
  • REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise SUBJECTIVE TYPE|4 Videos
  • SOLUTIONS

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 2.3 (Objective)|9 Videos

Similar Questions

Explore conceptually related problems

Given length of side of hexagonal unit cell is (100)/sqrt(2) pm . The volume of hexagonal unit cell is ("in" "pm"^(3)) :

The eccentricity of ellipse, if the distance between the foci and L.R is same a. (sqrt(3))/2 b. 2/(sqrt(3)) c. 1/(sqrt(2)) d. (sqrt(5)-1)/2

If the angles of a triangle are in the ratio 4:1:1, then the ratio of the longest side to the perimeter is (a) sqrt(3):(2+sqrt(3)) (b) 1:6 (c) 1:2+sqrt(3) (d) 2:3

A rectangle is inscribed in an equilateral triangle of side length 2a units. The maximum area of this rectangle can be (a) sqrt(3)a^2 (b) (sqrt(3)a^2)/4 a^2 (d) (sqrt(3)a^2)/2

The ratio of the areas of a circle and an equilateral triangle whose diameter and a side are respectively equal, is (a) pi\ :sqrt(2) (b) pi\ :sqrt(3) (c) sqrt(3)\ :pi (d) sqrt(2)\ :pi

The ratio of angles in a triangle ABC is 2:3:7 then prove that a:b:c=sqrt2:2:(sqrt3+1)

The ratio of the area of a square of side a and that of an equilateral triangle of side a , is (a) 2:1\ (b) 2:sqrt(3)\ (c) 4:3 (d) 4:sqrt(3)

Find the perpendicular distance of an angular point of a cube from a diagona which does not pass through that angular point. (a) (1)/sqrt3 (b) 2/3 (c) sqrt((2)/(3)) (d) (sqrt3)/2

If vec a\ a n d\ vec b are unit vectors, then which of the following values vec adot vec b is not possible? a. sqrt(3) b. sqrt(3)//2 c. 1//sqrt(2) d. -1//2

The direction ratio of the line OP are equal and the length OP=sqrt(3) . Then the coordinates of the point P are (A) (-1,-1,-1) (B) (sqrt(3),sqrt(3),sqrt(3)) (C) (sqrt(2),sqrt(2),sqrt(2)) (D) (2,2,2)

CENGAGE CHEMISTRY ENGLISH-SOLID STATE-Exercises (Single Correct)
  1. Consider the structure of CsCl (8: 8 coordination). How many Cs^(o+) i...

    Text Solution

    |

  2. A metal of density 7.5 xx 10^(3) kg m^(-3) has an fcc crystal structur...

    Text Solution

    |

  3. The ratio of the volume of a tetragonal lattice unit cell to that of a...

    Text Solution

    |

  4. An fcc lattice has a lattice parameter a = 400 pm. Calculater the mola...

    Text Solution

    |

  5. A TV in fcc is formed by atoms at

    Text Solution

    |

  6. A metal crystallizes in bcc lattice. The percent fraction of edge leng...

    Text Solution

    |

  7. In the cubic lattice given below, the three distances between the atom...

    Text Solution

    |

  8. In body-centred cubic lattice given below, the three disntances AB, AC...

    Text Solution

    |

  9. Two ionic solids AB and CB crystallize in the same lattice. If r(A^(o+...

    Text Solution

    |

  10. A molecule A(2)B (Mw = 166.4) occupies triclinic lattice with a = 5 Å,...

    Text Solution

    |

  11. Silicon dopped with group 13 and group 15 member element is, repective...

    Text Solution

    |

  12. Na and Mg crystallize in bcc- and fcc-type crystals, respectively, the...

    Text Solution

    |

  13. The electrical conductivity of semiconductor is

    Text Solution

    |

  14. Pure silicon and germanium behave as

    Text Solution

    |

  15. A solid has a structure in which W atoms are located at the corners of...

    Text Solution

    |

  16. Which of the following is a ferroelectric compound?

    Text Solution

    |

  17. The intermetallic compound LiAg crystallizes in cubic lattice in which...

    Text Solution

    |

  18. The edge length of a face-centred cubic unit cell is 508 p m. If the r...

    Text Solution

    |

  19. In the crystals of which of the following ionic compounds would you ex...

    Text Solution

    |

  20. Schottky defect is observed in crystals when

    Text Solution

    |