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If r(o+)//r(ɵ) for a crystal is 0.50, it...

If `r_(o+)//r_(ɵ)` for a crystal is `0.50`, it has ……….. structure.

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To determine the structure of a crystal based on the radius ratio \( \frac{r_{o+}}{r_{\theta}} \), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Given Ratio**: We are given the radius ratio \( \frac{r_{o+}}{r_{\theta}} = 0.50 \). Here, \( r_{o+} \) is the radius of the cation (positively charged ion) and \( r_{\theta} \) is the radius of the anion (negatively charged ion). 2. **Identify the Range for Radius Ratios**: We need to compare the given ratio with known ranges for different types of voids in crystal structures. The ranges are as follows: - Linear void: \( \frac{r_{o+}}{r_{\theta}} < 0.155 \) - Triangular void: \( 0.155 \leq \frac{r_{o+}}{r_{\theta}} < 0.225 \) - Tetrahedral void: \( 0.225 \leq \frac{r_{o+}}{r_{\theta}} < 0.414 \) - Octahedral void: \( 0.414 \leq \frac{r_{o+}}{r_{\theta}} < 0.732 \) - Cubical void: \( \frac{r_{o+}}{r_{\theta}} \geq 0.732 \) 3. **Determine the Type of Void**: Since \( 0.50 \) lies within the range \( 0.414 \leq \frac{r_{o+}}{r_{\theta}} < 0.732 \), we can conclude that the type of void present in the structure is octahedral. 4. **Conclude the Structure**: Given that the crystal has octahedral voids, we can say that the structure of the crystal is an octahedral structure. ### Final Answer: The crystal has an **octahedral structure**.
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