Home
Class 12
CHEMISTRY
If a crystal a contains a total of N ato...

If a crystal a contains a total of `N` atoms and `n` Schottky defects are produced by removing `n` cations and `r` anions from the interior of the crystal, then `n =` ……. .

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem regarding the number of Schottky defects in a crystal, we need to derive the expression for `n`, which represents the number of Schottky defects produced by removing `n` cations and `r` anions from the crystal. ### Step-by-Step Solution: 1. **Understanding Schottky Defects**: - Schottky defects occur when an equal number of cations and anions are removed from the crystal lattice. This maintains charge neutrality in the crystal. 2. **Defining Variables**: - Let `N` be the total number of atoms in the crystal. - Let `n` be the number of cations removed. - Let `r` be the number of anions removed. 3. **Charge Neutrality Condition**: - For a Schottky defect, the number of cations removed (`n`) must equal the number of anions removed (`r`). - Therefore, we can write: \[ n = r \] 4. **Total Number of Defects**: - The total number of Schottky defects (`n`) produced in the crystal can be expressed in terms of the total number of atoms and the energy required to create these defects. - The relationship can be given by the equation: \[ n = N \cdot e^{-\frac{E}{2kT}} \] - Here, `E` is the energy required to create a Schottky defect, `k` is Boltzmann's constant, and `T` is the temperature in Kelvin. 5. **Final Expression**: - From the above relationship, we can conclude that: \[ n = N \cdot e^{-\frac{E}{2kT}} \] ### Final Answer: Thus, the value of `n` (the number of Schottky defects) is given by: \[ n = N \cdot e^{-\frac{E}{2kT}} \]
Promotional Banner

Topper's Solved these Questions

  • SOLID STATE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (True/False)|19 Videos
  • SOLID STATE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Archives ) Linked Comprehension|3 Videos
  • SOLID STATE

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Interger)|9 Videos
  • REDUCTION AND OXIDATION REACTION OF ORGANIC COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise SUBJECTIVE TYPE|4 Videos
  • SOLUTIONS

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 2.3 (Objective)|9 Videos

Similar Questions

Explore conceptually related problems

The cations and anions are arranged n alternate form in:

Statement-1 :Schottky type of defect is shown by crystals with high co-ordination numbers . Statement-2 :In Schottky defect , equal number of cations and anions are missing from their lattice sites

Assertion (A) : The density of crystal having Schottky defect is lowered. Reason (R ) : The crystals suffering from Schottky defect have same number of cation and anions missing from their normal lattice sites.

For N atoms in a crystal with N_(i) interstitial position in its structure. If there are n Frenekel defects in the crystal, then n = ……. .

A : In Schottky defect, density of crystal decreases. R : Equal number of cations and anions are missing in Schottky defect.

Ionic lattic has two major points defects ,(1) Schottky (2) Frenkel defects . Schottkly defects occurs due to the cations - anion pair's missing from the lattice sites . Frenkel defects occurs when cation leaves its lattice site and fits into an interstitial space. The neutrality of the crystal is being maintained and we considered all losses from interstitial positions. which defect decrease density of the crystal ?

Ionic lattic has two major points defects ,(1) Schottky (2) Frenkel defects . Schottkly defects occurs due to the cations - anion pair's missing from the lattice sites . Frenkel defects occurs levels its lattic site and fits into an intersitial space. The neturaity of the crystal is benig maintained and we considerd all losses from interstitical positions. Structure shown here represents :

Ionic lattic has two major points defects ,(1) Schottky (2) Frenkel defects . Schottkly defects occurs due to the cations - anion pair's missing from the lattice sites . Frenkel defects occurs levels its lattic site and fits into an intersitial space. The neturaity of the crystal is benig maintained and we considerd all losses from interstitical positions. Structure shown here represents :

The number of Schottky defects (n) present in an ionic compound containing N ions at temperature T is given by n = Ne^(-E//2KT) , where E is the energy required to create n Schottky defects and K is the Boltzmann constant, If the mole fraction of Schottky defect in NaCl crystal at 2900 K is X , then calculate -ln(x) , Given: DeltaH of Schottky defect = 2 eV and K = 1.38 xx 10^(-23) J K^(-1) 1 eV = 1.608 xx 10^(-19) J

How can an n-type semiconductor be obtained from a purse crystal of Germanium ?