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Fe^(III) (Fe^(II) Fe^(III))O(4) represen...

`Fe^(III) (Fe^(II) Fe^(III))O_(4)` represent an inverse `2 : 3` spinel structre.True/False.

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To determine whether the statement "Fe^(III) (Fe^(II) Fe^(III))O_(4) represents an inverse 2:3 spinel structure" is true or false, we can follow these steps: ### Step 1: Understand the Inverse Spinel Structure An inverse spinel structure is generally represented as \( A^{2+}B^{3+}_2O_4 \). In this structure, the \( A^{2+} \) cations occupy the tetrahedral voids, and the \( B^{3+} \) cations occupy both tetrahedral and octahedral voids. ### Step 2: Identify the Components in the Given Formula The formula given is \( Fe^{III} (Fe^{II} Fe^{III})O_4 \). This can be interpreted as: - \( Fe^{II} \) = \( Fe^{2+} \) - \( Fe^{III} \) = \( Fe^{3+} \) - \( O \) = \( O^{2-} \) ### Step 3: Analyze the Cation Distribution In the inverse spinel structure: - The \( Fe^{3+} \) ions will occupy both tetrahedral and octahedral sites. - The \( Fe^{2+} \) ions will occupy the tetrahedral sites. ### Step 4: Count the Cations In the formula \( Fe^{III} (Fe^{II} Fe^{III})O_4 \): - There are 2 \( Fe^{3+} \) ions and 1 \( Fe^{2+} \) ion. - This gives a total of 3 \( Fe^{3+} \) ions and 1 \( Fe^{2+} \) ion, which fits the \( A^{2+}B^{3+}_2O_4 \) format. ### Step 5: Confirm the Structure In the structure: - The \( Fe^{3+} \) ions will occupy 1/8 tetrahedral and 1/4 octahedral voids. - The \( Fe^{2+} \) ions will occupy the remaining tetrahedral voids. ### Conclusion Since the distribution of cations matches the characteristics of an inverse spinel structure with a ratio of 2:3 (where 2 are \( Fe^{3+} \) and 1 is \( Fe^{2+} \)), the statement is **True**.

To determine whether the statement "Fe^(III) (Fe^(II) Fe^(III))O_(4) represents an inverse 2:3 spinel structure" is true or false, we can follow these steps: ### Step 1: Understand the Inverse Spinel Structure An inverse spinel structure is generally represented as \( A^{2+}B^{3+}_2O_4 \). In this structure, the \( A^{2+} \) cations occupy the tetrahedral voids, and the \( B^{3+} \) cations occupy both tetrahedral and octahedral voids. ### Step 2: Identify the Components in the Given Formula The formula given is \( Fe^{III} (Fe^{II} Fe^{III})O_4 \). This can be interpreted as: - \( Fe^{II} \) = \( Fe^{2+} \) ...
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