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For 1 molal solution of each compound m...

For 1 molal solution of each compound maximum freezing point will be assuming compete ionisation in each case :

A

`[Fe(H_(2)O)_(6)]Cl_(3)`

B

`[Fe(H_(2)O)_(5)Cl]Cl_(2).H_(2)O`

C

`[Fe(H_(2)O)_(4)Cl_(2)]Cl.2H_(2)O`

D

`[Fe(H_(2)O)_(3)Cl_(3)].3H_(2)O`

Text Solution

Verified by Experts

The correct Answer is:
D
Larger the value of (i), Smaller the freezing point (d) is a case of non-electrolytes, `i=1`
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For 1 molal solution of each compound minimum freezing point will be assuming compound ionisation in each case : (a) [Fe(H_(2)O)_(6)]Cl_(3) (b) [Fe(H_(2)O)_(5)Cl]Cl_(2) . H_(2)O (c) [Fe(H_(2)O)_(4)Cl_(2)]Cl .2 H_(2)O (d) [Fe(H_(2)O)_(3)Cl_(3)] .3 H_(2)O

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