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For the reduction of NO(3)^(c-) ion in a...

For the reduction of `NO_(3)^(c-)` ion in an aqueous solution, `E^(c-)` is `+0.96V`, the values of `E^(c-)` for some metal ions are given below `:`
`i.V^(2+)(aq)+2e^(-)rarr V, " "E^(c-)=-1.19V`
`ii. Fe^(3+)(aq)+3e^(-) rarr Fe, " "E^(c-)=-0.04V`
`iii. Au^(3+)(aq)+3e^(-) rarr Au, " "E^(c-)=+1.40V`
`iv. Hg^(2+)(aq)+2e^(-) rarr Hg, " "E^(c-)=+0.86V`
The pair`(s)` of metals that is `//` are oxidized by `NO_(3)^(c-)` in aqueous solution is `//` are

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To determine which pairs of metal ions are oxidized by the `NO3^-` ion in an aqueous solution, we need to compare the standard reduction potentials (E°) of the metal ions with that of the `NO3^-` ion. ### Step-by-Step Solution: 1. **Identify the Standard Reduction Potential of `NO3^-`:** The standard reduction potential for the reduction of `NO3^-` is given as: \[ E^\circ(\text{NO}_3^-/\text{NO}) = +0.96 \, \text{V} \] 2. **List the Standard Reduction Potentials of the Given Metal Ions:** The standard reduction potentials for the metal ions provided are: - \( V^{2+} + 2e^- \rightarrow V \), \( E^\circ = -1.19 \, \text{V} \) - \( Fe^{3+} + 3e^- \rightarrow Fe \), \( E^\circ = -0.04 \, \text{V} \) - \( Au^{3+} + 3e^- \rightarrow Au \), \( E^\circ = +1.40 \, \text{V} \) - \( Hg^{2+} + 2e^- \rightarrow Hg \), \( E^\circ = +0.86 \, \text{V} \) 3. **Compare the Standard Reduction Potentials:** To find which metal ions can be oxidized by `NO3^-`, we need to identify those with standard reduction potentials less than `+0.96 V` (since a higher reduction potential means a stronger oxidizing agent). - For \( V^{2+} \): \( -1.19 \, \text{V} < 0.96 \, \text{V} \) (can be oxidized) - For \( Fe^{3+} \): \( -0.04 \, \text{V} < 0.96 \, \text{V} \) (can be oxidized) - For \( Au^{3+} \): \( +1.40 \, \text{V} > 0.96 \, \text{V} \) (cannot be oxidized) - For \( Hg^{2+} \): \( +0.86 \, \text{V} < 0.96 \, \text{V} \) (can be oxidized) 4. **Identify the Pairs of Metals:** The metal ions that can be oxidized by `NO3^-` are: - \( V^{2+} \) - \( Fe^{3+} \) - \( Hg^{2+} \) 5. **Conclusion:** The pairs of metals that can be oxidized by `NO3^-` in aqueous solution are: - \( V^{2+} \) and \( Fe^{3+} \) - \( V^{2+} \) and \( Hg^{2+} \) - \( Fe^{3+} \) and \( Hg^{2+} \) ### Final Answer: The pairs of metals that are oxidized by `NO3^-` in aqueous solution are \( V^{2+}, Fe^{3+} \) and \( Hg^{2+} \).

To determine which pairs of metal ions are oxidized by the `NO3^-` ion in an aqueous solution, we need to compare the standard reduction potentials (E°) of the metal ions with that of the `NO3^-` ion. ### Step-by-Step Solution: 1. **Identify the Standard Reduction Potential of `NO3^-`:** The standard reduction potential for the reduction of `NO3^-` is given as: \[ E^\circ(\text{NO}_3^-/\text{NO}) = +0.96 \, \text{V} ...
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