Home
Class 12
CHEMISTRY
A zinc electrode is placed in 0.1M solut...

A zinc electrode is placed in `0.1M` solution of `ZnSO_(4)` at `25^(@)C`. Assuming salt is dissociated to the extent of `20%` at this dilution. The potential. The potential of this electrode at this temperature is `:`
`(E^(c-)._(Zn^(2+)|Zn)=-0.76V)`
`a. 0.79V" ".b. -0.79V" "c. -0.81V." "d. 0.81V`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will follow these steps: ### Step 1: Determine the concentration of Zn²⁺ ions Given that the zinc sulfate (ZnSO₄) solution is 0.1 M and it dissociates to the extent of 20%, we can calculate the concentration of Zn²⁺ ions. - **Dissociation of ZnSO₄**: \[ \text{ZnSO}_4 \rightarrow \text{Zn}^{2+} + \text{SO}_4^{2-} \] - **Concentration of Zn²⁺**: \[ \text{Concentration of Zn}^{2+} = 0.1 \, \text{M} \times 0.20 = 0.02 \, \text{M} \] ### Step 2: Use the Nernst equation The Nernst equation relates the cell potential to the standard electrode potential and the concentrations of the reactants and products. - **Nernst equation**: \[ E = E^\circ - \frac{0.0591}{n} \log Q \] where: - \(E^\circ\) is the standard reduction potential, - \(n\) is the number of moles of electrons transferred, - \(Q\) is the reaction quotient. ### Step 3: Identify the parameters From the problem: - \(E^\circ_{\text{Zn}^{2+}/\text{Zn}} = -0.76 \, \text{V}\) - \(n = 2\) (since \( \text{Zn}^{2+} + 2e^- \rightarrow \text{Zn} \)) - \(Q = \frac{1}{[\text{Zn}^{2+}]} = \frac{1}{0.02} = 50\) ### Step 4: Substitute values into the Nernst equation Now we can substitute the values into the Nernst equation: \[ E = -0.76 - \frac{0.0591}{2} \log(50) \] ### Step 5: Calculate \(\log(50)\) Using logarithmic properties: \[ \log(50) = \log(5 \times 10) = \log(5) + \log(10) \approx 0.7 + 1 = 1.7 \] ### Step 6: Substitute \(\log(50)\) back into the equation Now substituting \(\log(50)\) back into the equation: \[ E = -0.76 - \frac{0.0591}{2} \times 1.7 \] \[ E = -0.76 - 0.02955 \times 1.7 \] \[ E = -0.76 - 0.050235 \] \[ E \approx -0.81 \, \text{V} \] ### Final Answer Thus, the potential of the zinc electrode in the given conditions is approximately: \[ \boxed{-0.81 \, \text{V}} \]

To solve the problem, we will follow these steps: ### Step 1: Determine the concentration of Zn²⁺ ions Given that the zinc sulfate (ZnSO₄) solution is 0.1 M and it dissociates to the extent of 20%, we can calculate the concentration of Zn²⁺ ions. - **Dissociation of ZnSO₄**: \[ \text{ZnSO}_4 \rightarrow \text{Zn}^{2+} + \text{SO}_4^{2-} ...
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Solved Examples (Electrochemical Cell)|36 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Solved Examples(Electrolysis And Electrolytic Cells)|12 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|29 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives (Subjective)|14 Videos

Similar Questions

Explore conceptually related problems

At what pH the potential of Hydrogen electrode will be 0.059 V?

What is the effect of increase in concentration of zinc ions on the electrode potential of zinc electrode for which E_(Zn^(2+)//Zn) equals - 0.76 V

At What pH oxidation potential of water is -0.81V ?

A zinc rod dipped in n molar solution of ZnSO_4 has an electrode potential of -0.56 V. The salt is 98 percent dissociated at room temperature. What is the molarity of the solution? (E°(Zn^(+2)/Zn) = -0.5 V)

Standard reduction electrode potential of Zn^(2+)//Zn is -0.76V . This means:

Calculate the standard potential of the cell ,If the standard electrode potentials of Zn^(2+)//Zn and Ag^(+) //Ag are -0.763 V and + 0.799 V respectively .

E^@ of zinc electrode is -0.762V . Calculate the single electrode potential of Zn electrode in decimolar ZnSO_4 solution.

Calculate the maximum work that can be obtained from the decimolar Daniell cell at 25^(@)C . Given E^(c-)._((Zn^(2+)|Zn))=-0.76V and E^(c-)._((Cu^(2+)|Cu))=0.34V

At 25^@C , the reduction potential of hydrogen electrode is -0.118 V at 1 atm. What is the pH of acid solution used for the construction of the electrode?

A galvanic cell consists of a metallic zinc plate immersed in 0.1 M Zn (NO_(3))_(2) solution and metallic plate of lead in 0.02M Pb(NO_(3))_(2) solution. Calculate the emf of the cell. Write the chemical equation for the electrode reactions and represent the cell. ("Given" : E^(@) Zn^(2+)ZN=0.76V, " " E^(@)Pb^(2+)//Pb = -0.13V)

CENGAGE CHEMISTRY ENGLISH-ELECTROCHEMISTRY-Archieves Subjective
  1. A zinc electrode is placed in 0.1M solution of ZnSO(4) at 25^(@)C. Ass...

    Text Solution

    |

  2. A current of 3.7 A is passed for 6hrs. Between Ni electrodes in 0.5 L ...

    Text Solution

    |

  3. Consider the cell : Zn|Zn^(2+)(aq)(1.0M)||Cu^(2+)(aq)(1.0M)||Cu Th...

    Text Solution

    |

  4. In an electrolysis experiment, current was passed for 5h through two c...

    Text Solution

    |

  5. How long a current of 3A has to be passed through a solution of silver...

    Text Solution

    |

  6. Give reasons in one or two sentences :" anhydrous HCl is a bad conduc...

    Text Solution

    |

  7. The EMF of the following cellis 1.05V at 25^(@)C: Pt,H(2)(g)(1.0 atm...

    Text Solution

    |

  8. During the discharge of a lead storage battery, the density of sulphur...

    Text Solution

    |

  9. A 100 watt, 110 volt incandescent lamp is connected in series with an ...

    Text Solution

    |

  10. A cell contains two hydrogen electrodes. The negative electrode is in ...

    Text Solution

    |

  11. In a fuel cell, hydrogen and oxygen react to produce electricity. In p...

    Text Solution

    |

  12. An acidic solution of Cu^(2+0 salt containing 0.4g of Cu^(2+) is elect...

    Text Solution

    |

  13. Define Photolytic decomposition reaction.

    Text Solution

    |

  14. The standard reduction potential of Cu^(2+)|Cu and Ag^(o+)|Ag electrod...

    Text Solution

    |

  15. Calculate the quantity of electricity that would be required to reduce...

    Text Solution

    |

  16. Zinc granules are added in excess to 500mL OF 1.0m nickel nitrate solu...

    Text Solution

    |

  17. During the electrolysis of an aqueoius nitric acid solution using pt e...

    Text Solution

    |

  18. The standard reduction potential of Ag^(+)//Ag electrode at 298 K is 0...

    Text Solution

    |

  19. An aqueous solution of NaCl on electrolysis gives H(2)(g), Cl(2)(g), a...

    Text Solution

    |

  20. The standard reduction potential for the half cell : NO(3)^(c-)(aq)+...

    Text Solution

    |

  21. Chromium metal is electroplated using an acidic solution containing Cr...

    Text Solution

    |