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The EMF of the cell : Cd|CdCl(2)( sol...

The `EMF` of the cell `:`
`Cd|CdCl_(2)(` solution `)(1atm)|AgCl(s)|Ag` is `0.675` at `25^(@)C`. The temperature coefficient of the cell is `-6.5xx10^(-4)` `d e g r e e^(-1)`. Find the change in heat content and entropy for the electrochemical reaction that occurs when `1F` of electricity is drawn for it.

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To solve the problem, we will follow these steps: ### Step 1: Calculate the change in entropy (ΔS) The change in entropy for the electrochemical reaction can be calculated using the formula: \[ \Delta S = -nF \left( \frac{dE}{dT} \right)_{P} \] Where: ...
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