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Consider the cell reaction : Mg(s)+Cu^...

Consider the cell reaction `:`
`Mg(s)+Cu^(2+)(aq) rarr Cu(s) +Mg^(2+)(aq)`
If `E^(c-)._(Mg^(2+)|Mg(s))` and `E^(c-)._(Cu^(2+)|Cu(s))` are `-2.37` and `0.34V`, respectively. `E^(c-)._(cell)` is

A

`2.03V`

B

`-2.03V`

C

`-2.17 V`

D

`2.71 V`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will follow these steps: ### Step 1: Identify the half-reactions and their standard reduction potentials The cell reaction is: \[ \text{Mg(s)} + \text{Cu}^{2+}(aq) \rightarrow \text{Cu(s)} + \text{Mg}^{2+}(aq) \] From the problem, we have the following standard reduction potentials: - For the reduction of magnesium: \[ \text{Mg}^{2+} + 2e^- \rightarrow \text{Mg(s)} \quad E^\circ = -2.37 \, \text{V} \] - For the reduction of copper: \[ \text{Cu}^{2+} + 2e^- \rightarrow \text{Cu(s)} \quad E^\circ = 0.34 \, \text{V} \] ### Step 2: Determine the anode and cathode In this reaction: - Magnesium (Mg) is oxidized to magnesium ions (Mg²⁺), so it acts as the anode. - Copper ions (Cu²⁺) are reduced to copper metal (Cu), so it acts as the cathode. ### Step 3: Write the formula for the cell potential The standard cell potential \( E^\circ_{\text{cell}} \) can be calculated using the formula: \[ E^\circ_{\text{cell}} = E^\circ_{\text{cathode}} - E^\circ_{\text{anode}} \] ### Step 4: Substitute the values into the formula Here, the cathode is Cu²⁺ and the anode is Mg: - \( E^\circ_{\text{cathode}} = 0.34 \, \text{V} \) - \( E^\circ_{\text{anode}} = -2.37 \, \text{V} \) Now substituting these values: \[ E^\circ_{\text{cell}} = 0.34 \, \text{V} - (-2.37 \, \text{V}) \] \[ E^\circ_{\text{cell}} = 0.34 \, \text{V} + 2.37 \, \text{V} \] \[ E^\circ_{\text{cell}} = 2.71 \, \text{V} \] ### Step 5: Conclusion The standard cell potential \( E^\circ_{\text{cell}} \) is: \[ \boxed{2.71 \, \text{V}} \] ---

To solve the problem, we will follow these steps: ### Step 1: Identify the half-reactions and their standard reduction potentials The cell reaction is: \[ \text{Mg(s)} + \text{Cu}^{2+}(aq) \rightarrow \text{Cu(s)} + \text{Mg}^{2+}(aq) \] From the problem, we have the following standard reduction potentials: - For the reduction of magnesium: ...
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