Home
Class 12
CHEMISTRY
For the reaction : A+2B^(3+) rarr 2B^(...

For the reaction `:`
`A+2B^(3+) rarr 2B^(2+)+A^(2+)`
`E^(c-)` of the given redox reaction is `:`
`A^(2+)+2e^(-) rarr A` `E^(c-)=Xv`
`B^(3+)+e^(-) rarr B^(2+)` `E^(c-)=yV`

A

`x-2y`

B

`x+y//2`

C

`x-y`

D

`y-x`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the standard cell potential (E°cell) for the given redox reaction: **Given Reaction:** \[ A + 2B^{3+} \rightarrow 2B^{2+} + A^{2+} \] **Half-Reactions:** 1. Oxidation (Anode): \[ A \rightarrow A^{2+} + 2e^{-} \] The standard reduction potential for this half-reaction is given as: \[ E^{\circ}_{\text{oxidation}} = -X \, \text{V} \] Therefore, the standard reduction potential for the reverse reaction (reduction) is: \[ E^{\circ}_{\text{reduction}} = X \, \text{V} \] 2. Reduction (Cathode): \[ 2B^{3+} + 2e^{-} \rightarrow 2B^{2+} \] The standard reduction potential for this half-reaction is given as: \[ E^{\circ}_{\text{reduction}} = Y \, \text{V} \] **Calculating E°cell:** The standard cell potential (E°cell) can be calculated using the formula: \[ E^{\circ}_{\text{cell}} = E^{\circ}_{\text{cathode}} - E^{\circ}_{\text{anode}} \] Substituting the values: - The cathode reaction (reduction of B) has a potential of \( Y \, \text{V} \). - The anode reaction (oxidation of A) has a potential of \( X \, \text{V} \). Thus, we have: \[ E^{\circ}_{\text{cell}} = Y - X \] **Final Answer:** The total standard cell potential for the given redox reaction is: \[ E^{\circ}_{\text{cell}} = (Y - X) \, \text{V} \] ---

To solve the problem, we need to determine the standard cell potential (E°cell) for the given redox reaction: **Given Reaction:** \[ A + 2B^{3+} \rightarrow 2B^{2+} + A^{2+} \] **Half-Reactions:** 1. Oxidation (Anode): \[ A \rightarrow A^{2+} + 2e^{-} \] ...
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 3.2 (Objective)|26 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 3.3 (Objective)|10 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Solved Examples(Electrolysis And Electrolytic Cells)|12 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|29 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives (Subjective)|14 Videos

Similar Questions

Explore conceptually related problems

For a reaction A + 2B rarr C , rate is given by R = K [A] [B]^(2) . The order of reaction is:

1/2 F_(2)+e^(-) rarr F^(-)" "E^(@)=+3.02V Electrode potential for given reaction F_(2)+2e^(-) rarr 2F^(-)

For a reaction: A(s) + 2B ^(+) rarr A^(2+) +2 B (s). K_(aq) has been found to be 10^(12) The E^(o) cell is :

For a reaction A(s) + 2B^(+) rarr A^(2+)+2B(s). K_(c) has been found to be 10^(14) The E^(o) ""_(cell) is :

For the reaction, A (g) + 2B(g) rarr 2C(g) + 3D(g) the change of enthalpy at 27^@C is 19 kcal. The value of Delta E is:

For a reaction A(s)+2B^(o+) rarr A^(2+)+2B K_(c) has been found to be 10^(12) . The E^(c-)._(cell) is

Half cell reactions for some electrodes are given below I. A + e^(-) rarr A^(-) , E^(@) = 0.96V II. B^(-) + e^(-) rarr B^(2-) , E^(@) = -0.12V III. C^(+) + e^(-) rarr C, E^(@) =+0.18V IV. D^(2+) + 2e^(-) rarr D, E^(@) = -1.12V Largest potential will be generated in which cell?

Redox reactions play a pivotal role in chemistry and biology. The values standard redox potential (E^(c-)) of two half cell reactions decided which way the reaction is expected to preceed. A simple example is a Daniell cell in which zinc goes into solution and copper sets deposited. Given below are a set of half cell reactions ( acidic medium ) along with their E^(c-)(V with respect to normal hydrogen electrode ) values. Using this data, obtain correct explanations for Question. I_(2)+2e^(-) rarr 2I^(c-)," "E^(c-)=0.54 Cl_(2)+2e^(-) rarr 2Cl^(c-), " "E^(c-)=1.36 Mn^(3+)+e^(-) rarr Mn^(2+), " "E^(c-)=1.50 Fe^(3+)+e^(-) rarr Fe^(2+)," "E^(c-)=0.77 O_(2)+4H^(o+)+4e^(-) rarr 2H_(2)O, " "E^(c-)=1.23 Among the following, identify the correct statement. (a)Chloride ion is oxidized by O_(2) . (b) Fe^(2+) is oxidized by iodine. (c)Iodide ion is oxidized by chlorine (d) Mn^(2+) is oxidized by chlorine.

For the reduction of NO_(3)^(c-) ion in an aqueous solution, E^(c-) is +0.96V , the values of E^(c-) for some metal ions are given below : i.V^(2+)(aq)+2e^(-)rarr V, " "E^(c-)=-1.19V ii. Fe^(3+)(aq)+3e^(-) rarr Fe, " "E^(c-)=-0.04V iii. Au^(3+)(aq)+3e^(-) rarr Au, " "E^(c-)=+1.40V iv. Hg^(2+)(aq)+2e^(-) rarr Hg, " "E^(c-)=+0.86V The pair (s) of metals that is // are oxidized by NO_(3)^(c-) in aqueous solution is // are

For the reduction of NO_(3)^(c-) ion in an aqueous solution, E^(c-) is +0.96V , the values of E^(c-) for some metal ions are given below : i.V^(2+)(aq)+2e^(-)rarr V, " "E^(c-)=-1.19V ii. Fe^(3+)(aq)+3e^(-) rarr Fe, " "E^(c-)=-0.04V iii. Au^(3+)(aq)+3e^(-) rarr Au, " "E^(c-)=+1.40V iv. Hg^(2+)(aq)+2e^(-) rarr Hg, " "E^(c-)=+0.86V The pair (s) of metals that is // are oxidized by NO_(3)^(c-) in aqueous solution is // are

CENGAGE CHEMISTRY ENGLISH-ELECTROCHEMISTRY-Ex 3.1 (Objective)
  1. If all species are in their standard states, which of the following is...

    Text Solution

    |

  2. The standard EMF fo a galvanic cell involving cell reaction with n=2 i...

    Text Solution

    |

  3. The correct order of reactivity of K,Mg,Zn and Cu with water according...

    Text Solution

    |

  4. For Pt(H(2))|H(2)O , reduction potential at 298 K and 1 atm is :

    Text Solution

    |

  5. Represent the cell for the reaction Mg(s)+Cu(aq)^(+2)rarrMg(aq)^(+2)...

    Text Solution

    |

  6. If E^(c-).(Fe^(3+)|Fe) and E^(c-).(Fe^(2+)|Fe) are =-0.36 V and -0.439...

    Text Solution

    |

  7. Pt(Cl(2))(p(1))|HCl(0.1M)|(Cl(2))(p(2)),Pt cell reaction will be ender...

    Text Solution

    |

  8. Consider the following cell with hydrogen electrodes at difference pre...

    Text Solution

    |

  9. Consider the following cell reaction Zn +2Ag^(o+)rarr Zn ^(2+)+2Ag....

    Text Solution

    |

  10. Standard electrode potential of three metals X, Y and Z are -1.2V,+0.5...

    Text Solution

    |

  11. Calculate the maximum work that can be obtained from the decimolar Dan...

    Text Solution

    |

  12. Stronger the oxidizing agent, greater is the

    Text Solution

    |

  13. Consider the cell Ag(s)|AgBr(s)Br^(c-)(aq)||AgCl(s),Cl^(c-)(aq)|Ag(s) ...

    Text Solution

    |

  14. The pH of LHE in the following cell is : Pt, H(2)(1atm)|H^(o+)(x M)...

    Text Solution

    |

  15. At what concentration of [overset(c-)(O)H] does the following half rea...

    Text Solution

    |

  16. If hydrogen electrodes dipped in two solutions of pH=3 and pH=6 are co...

    Text Solution

    |

  17. Consider the cell reaction : Mg(s)+Cu^(2+)(aq) rarr Cu(s) +Mg^(2+)(a...

    Text Solution

    |

  18. E^(c-).(red) of different half cell are given as : E^(c-).(Cu^(2+)|C...

    Text Solution

    |

  19. For the reaction : A+2B^(3+) rarr 2B^(2+)+A^(2+) E^(c-) of the giv...

    Text Solution

    |

  20. Excess of solid AgCl is added to a 0.1 M solution of Br^(c-) ions. E^(...

    Text Solution

    |