Home
Class 12
CHEMISTRY
According of Kohlrausch law, the limitin...

According of Kohlrausch law, the limiting value of molar conductivity of an electrolyte `A_(2)B` is
(a)`lambda^(oo) ._(A^(+)) + lambda^(oo) ._((B^(-))`
(b)`lambda^(oo) ._(A^(+)) - lambda^(oo) ._(B^(-))`
(c)`2lambda^(oo) ._(A^(+)) +(1)/(2)lambda^(oo) ._((B^(-))`
(d)`2lambda^(oo) ._(A^(+)) + lambda^(oo) ._(B^(-))`

A

`lambda^(oo) ._(A^(+)) + lambda^(oo) ._((B^(-))`

B

`lambda^(oo) ._(A^(+)) - lambda^(oo) ._(B^(-))`

C

`2lambda^(oo) ._(A^(+)) +(1)/(2)lambda^(oo) ._((B^(-))`

D

`2lambda^(oo) ._(A^(+)) + lambda^(oo) ._(B^(-))`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the limiting value of molar conductivity of the electrolyte \(A_2B\) according to Kohlrausch's law, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Electrolyte Dissociation:** The electrolyte \(A_2B\) dissociates in solution to form ions. The dissociation can be represented as: \[ A_2B \rightarrow 2A^+ + B^{2-} \] This means that for each formula unit of \(A_2B\), we get 2 moles of \(A^+\) ions and 1 mole of \(B^{2-}\) ions. 2. **Applying Kohlrausch's Law:** According to Kohlrausch's law, the molar conductivity \(\Lambda^{\infty}\) of an electrolyte at infinite dilution is the sum of the contributions from its cations and anions: \[ \Lambda^{\infty}(A_2B) = \nu_+ \lambda^{\infty}(A^+) + \nu_- \lambda^{\infty}(B^{2-}) \] where \(\nu_+\) and \(\nu_-\) are the stoichiometric coefficients of the cation and anion, respectively, and \(\lambda^{\infty}\) represents the molar conductivity at infinite dilution. 3. **Identifying Stoichiometric Coefficients:** From the dissociation reaction, we see that: - The stoichiometric coefficient for \(A^+\) is \(2\) (since there are 2 moles of \(A^+\)). - The stoichiometric coefficient for \(B^{2-}\) is \(1\) (since there is 1 mole of \(B^{2-}\)). 4. **Writing the Expression:** Substituting the stoichiometric coefficients into the equation, we get: \[ \Lambda^{\infty}(A_2B) = 2\lambda^{\infty}(A^+) + 1\lambda^{\infty}(B^{2-}) \] This simplifies to: \[ \Lambda^{\infty}(A_2B) = 2\lambda^{\infty}(A^+) + \lambda^{\infty}(B^{2-}) \] 5. **Choosing the Correct Option:** Now, we look at the options provided: - (a) \(\lambda^{\infty}(A^+) + \lambda^{\infty}(B^{-})\) - (b) \(\lambda^{\infty}(A^+) - \lambda^{\infty}(B^{-})\) - (c) \(2\lambda^{\infty}(A^+) + \frac{1}{2}\lambda^{\infty}(B^{-})\) - (d) \(2\lambda^{\infty}(A^+) + \lambda^{\infty}(B^{-})\) The expression we derived matches option (d). ### Final Answer: The correct answer is (d) \(2\lambda^{\infty}(A^+) + \lambda^{\infty}(B^{2-})\).

To solve the question regarding the limiting value of molar conductivity of the electrolyte \(A_2B\) according to Kohlrausch's law, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding the Electrolyte Dissociation:** The electrolyte \(A_2B\) dissociates in solution to form ions. The dissociation can be represented as: \[ A_2B \rightarrow 2A^+ + B^{2-} ...
Promotional Banner

Topper's Solved these Questions

  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exerciseassertion -Reasoning|25 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exerciseinterger|8 Videos
  • ELECTROCHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercisemultiple Correct Ansers|53 Videos
  • D AND F BLOCK ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|29 Videos
  • GENERAL PRINCIPLES AND PROCESS OF ISOLATION OF ELEMENTS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives (Subjective)|14 Videos

Similar Questions

Explore conceptually related problems

Calculate the value of equivalent conductivity of MgCl_(2) at infinite dilution if lambda^(oo)(Mg^(2+))= 106.12 "ohm"^(-1)cm^(-2)"mol"^(-1), lambda^(oo)(Cl^(-))=76.34"ohm"^(-1)cm^(2)"mol"^(-1) .

At infinite dilution, the equivalent conductivity of the electrolyte is given by the expression: ^^^_(eq)^(oo)=lambda_((+))^(oo)+lambda_((-))^(oo) The above expression is given by

Two particle are moving perpendicular to each with de-Broglie wave length lambda_(1) and lambda_(2) . If they collide and stick then the de-Broglie wave length of system after collision is : (A) lambda = (lambda_(1) lambda_(2))/(sqrt(lambda_(1)^(2) + lambda_(2)^(2))) (B) lambda = (lambda_(1))/(sqrt(lambda_(1)^(2) + lambda_(2)^(2))) (C) lambda = (sqrt(lambda_(1)^(2) + lambda_(2)^(2)))/(lambda_(2)) (D) lambda = (lambda_(1) lambda_(2))/(sqrt(lambda_(1) + lambda_(2)))

Transition between three energy energy levels in a particular atom give rise to three Spectral line of wevelength , in increasing magnitudes. lambda_(1), lambda_(2) and lambda_(3) . Which one of the following equations correctly ralates lambda_(1), lambda_(2) and lambda_(3) ? lambda_(1)=lambda_(2)-lambda_(3) lambda_(1)=lambda_(3)-lambda_(2) (1)/(lambda_(1))=(1)/(lambda_(2))+(1)/(lambda_(3)) (1)/(lambda_(2))=(1)/(lambda_(3))+(1)/(lambda_(1))

The values of ^^_(m)^(oo) for KCl and KNO_(3) are 149.86 and 154.96Omega^(-1)cm^(2)"mol"^(-1) . Also lambda_(Cl)^(oo) is 71.44 ohm^(-1)cm^(2) "mol"^(-1) . The value of lambda_(NO_(3)^(-))^(oo) is

Calculate the dissociation constant of water at 25^(@)C from the following data. Specific conductance of H_(2)O = 5.8 xx 10^(-8) mho cm^(-1), lambda_(H^(+))^(oo) = 350.0 and lambda_(OH^(-))^(oo) = 198.0 mho cm^(2)

If the matrix A = [[lambda_(1)^(2), lambda_(1)lambda_(2), lambda_(1) lambda_(3)],[lambda_(2)lambda_(1),lambda_(2)^(2),lambda_(2)lambda_(3)],[lambda_(3)lambda_(1),lambda_(3)lambda_(2),lambda_(3)^(2)]] is idempotent, the value of lambda_(1)^(2) + lambda_(2)^(2) + lambda _(3)^(2) is

The interval of increase of the function f(x)=x-e^x+tan(2pi//7) is (a) (0,\ oo) (b) (-oo,\ 0) (c) (1,\ oo) (d) (-oo,\ 1)

If A satisfies the equation x^3-5x^2+4x+lambda=0 , then A^(-1) exists if (a) lambda!=1 (b) lambda!=2 (c) lambda!=-1 (d) lambda!=0

X-ray are produced in an X-ray tube operating at a given accelerating voltage. The wavelength of the continuous X-ray has values from. (a) 0 to oo (b) lambda_(min) to oo, where lambda_(min) gt 0 (c ) 0 to lambda_(max), where lambda_(max) ltoo (d) lambda_(min) ot lambda_(max) , where 0ltlambda(min) lt lambda_(max) lt oo

CENGAGE CHEMISTRY ENGLISH-ELECTROCHEMISTRY-Exercises Ingle Correct
  1. By virtue of Faraday's second law of electrolysis, the electrochemical...

    Text Solution

    |

  2. The units of conductivity of the solution are

    Text Solution

    |

  3. According of Kohlrausch law, the limiting value of molar conductivity ...

    Text Solution

    |

  4. The values of wedge(m)^(oo) forNH(4)Cl,NaOH, and NaCl are, respectivel...

    Text Solution

    |

  5. 0.5F of electricity is passed through 500mL of copper sulphate solutio...

    Text Solution

    |

  6. On carrying out the electrolysis of acidified water, the volume of hyd...

    Text Solution

    |

  7. During the electrolysis of the aqueous solution of copper sulphate usi...

    Text Solution

    |

  8. In passing 3F of electricity through three electrolytic cells connect ...

    Text Solution

    |

  9. Given that I(2)+2e^(-) rarr 2I^(c-)," "E^(c-)=0.54V Br(2)+2e^(...

    Text Solution

    |

  10. The increase in the molar conductivity of HCl with dilution is due to

    Text Solution

    |

  11. An electrochemical cell stops working after some time because

    Text Solution

    |

  12. Which of the following statements is correct for a galvanic cell?

    Text Solution

    |

  13. GivenE^(c-).(Ag^(o+)|Ag)=+0.80V, E^(c-).(Co^(2)|Co)=-0.28V, E^(c-). ...

    Text Solution

    |

  14. Red hot carbon will remove oxygen from the oxides XO and Yo but not fr...

    Text Solution

    |

  15. Among Na,Hg,S,Pt and graphite which can be used as electodes in electr...

    Text Solution

    |

  16. In an electrolytic cell current flows

    Text Solution

    |

  17. The reaction Cu^(2+)(aq)+2Cl^(-)(aq) rarr Cu(s)+Cl(2)(g) has E^(c-).(c...

    Text Solution

    |

  18. Which statements is true about a spontaneous cell reaction in galvanic...

    Text Solution

    |

  19. Zn acts as sacrifical or cathodic protecion to prevent rusting of iron...

    Text Solution

    |

  20. The oxidation potential of a hydrogen electrode at pH=10 and p(H(2))=1...

    Text Solution

    |