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Which of the following statements is wro...

Which of the following statements is wrong ?

A

The conductance of `1 cm^(3)` of a material is called specific conductance.

B

Specific conductance increases while equilvalent conductance decreases on progressive dilution.

C

The limiting equivalent conductances of weak electrolytes cannot be determined by the extrapolation of the plot of `wedge` against concentration.

D

The conductivity of metals is due to the movement of electrons.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statement is wrong, we will analyze each of the provided options step by step. ### Step 1: Analyze Option 1 **Statement:** The conductance of 1 cm³ form of a material is called specific conductance. **Analysis:** - Specific conductance (also known as conductivity) is defined as the conductance of a solution with a length of 1 cm and a cross-sectional area of 1 cm². - The formula for specific conductance (K) is given by K = G * (L/A), where G is the conductance, L is the length, and A is the area. - Since this definition is accurate, **Option 1 is true**. ### Step 2: Analyze Option 2 **Statement:** The specific conductance increases while equivalent conductance decreases on progressive dilution. **Analysis:** - When a solution is diluted, the number of ions present decreases, leading to a decrease in specific conductance. - However, the equivalent conductance (which is the conductance per equivalent of solute) increases upon dilution because the degree of ionization increases, allowing more ions to contribute to conductance. - Therefore, this statement contradicts the established principles of electrochemistry. **Option 2 is false**. ### Step 3: Analyze Option 3 **Statement:** The limiting equivalent conductance of weak electrolytes cannot be determined by the extrapolation of the plot of molar conductance against concentration. **Analysis:** - For weak electrolytes, when plotting molar conductance against concentration, the graph typically shows a curve rather than a straight line. - The limiting equivalent conductance can be determined by extrapolating the graph to zero concentration, but it is not straightforward due to the non-linear behavior. - Thus, this statement is correct in its assertion that limiting equivalent conductance cannot be easily determined from such a plot. **Option 3 is true**. ### Step 4: Analyze Option 4 **Statement:** The conductivity of metals is due to the movement of electrons. **Analysis:** - This statement is accurate. The conductivity in metals arises from the movement of free electrons, which are abundant in metallic structures. - As temperature increases, the vibrations of the metal lattice increase, which can impede electron flow, leading to decreased conductivity. - Therefore, this statement is also true. **Option 4 is true**. ### Conclusion After analyzing all options, we find that **Option 2 is the wrong statement**.

To determine which statement is wrong, we will analyze each of the provided options step by step. ### Step 1: Analyze Option 1 **Statement:** The conductance of 1 cm³ form of a material is called specific conductance. **Analysis:** - Specific conductance (also known as conductivity) is defined as the conductance of a solution with a length of 1 cm and a cross-sectional area of 1 cm². - The formula for specific conductance (K) is given by K = G * (L/A), where G is the conductance, L is the length, and A is the area. ...
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