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The resistance of 1N solution of acetic ...

The resistance of `1N` solution of acetic acid is `250ohm`, when measured in a cell of cell constant `1.15 cm^(-1)`. The equivalent conductance `(` in `ohm^(-1) cm^(2)eq^(-1))` of `1N` acetic acid is

A

`4.6`

B

`9.2`

C

`18.4`

D

`0.023`

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The correct Answer is:
To find the equivalent conductance of a 1N solution of acetic acid, we can follow these steps: ### Step 1: Understand the formula for conductivity (k) The conductivity (k) can be calculated using the formula: \[ k = \frac{Cell \ Constant}{Resistance} \] ### Step 2: Substitute the values for cell constant and resistance From the question, we know: - Cell constant = 1.15 cm\(^{-1}\) - Resistance = 250 ohms Substituting these values into the formula gives: \[ k = \frac{1.15 \ cm^{-1}}{250 \ \Omega} \] ### Step 3: Calculate the conductivity (k) Now, we perform the calculation: \[ k = \frac{1.15}{250} = 0.0046 \ \text{S cm}^{-1} \] (Note: 1 S = 1 Ohm\(^{-1}\)) ### Step 4: Use the formula for equivalent conductance (λ_eq) The equivalent conductance (λ_eq) can be calculated using the formula: \[ \lambda_{eq} = \frac{1000 \cdot k}{n} \] where \(n\) is the normality of the solution. ### Step 5: Substitute the values into the equivalent conductance formula Given that the normality \(n\) of the acetic acid solution is 1N, we substitute the values: \[ \lambda_{eq} = \frac{1000 \cdot 0.0046 \ \text{S cm}^{-1}}{1} \] ### Step 6: Calculate the equivalent conductance (λ_eq) Now, we perform the calculation: \[ \lambda_{eq} = 1000 \cdot 0.0046 = 4.6 \ \text{S cm}^2 \text{eq}^{-1} \] ### Final Answer The equivalent conductance of 1N acetic acid is: \[ \lambda_{eq} = 4.6 \ \text{ohm}^{-1} \text{cm}^2 \text{eq}^{-1} \] ---

To find the equivalent conductance of a 1N solution of acetic acid, we can follow these steps: ### Step 1: Understand the formula for conductivity (k) The conductivity (k) can be calculated using the formula: \[ k = \frac{Cell \ Constant}{Resistance} \] ...
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