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Given electrode potentials asre Fe^(3+...

Given electrode potentials asre
`Fe^(3+)+e^(-) rarr Fe^(2+)," "E^(c-)=0.771V`
` I_(2)+2e^(-) rarr 2I^(c-)," "E^(c-)=0.536V`
`E^(c-)._(cell)` for the cell reaction,
`Fe^(3+)+2I^(c-) rarr Fe^(2+)+I_(2)` is

A

`(2xx0.771-0.536)=1.006V`

B

`(0.771-0.5xx0.536)=0.503V`

C

`(0.771-0.536)=0.235V`

D

`(0.536-0.771)=0.236V`

Text Solution

AI Generated Solution

The correct Answer is:
To find the cell potential \( E_{cell} \) for the reaction: \[ \text{Fe}^{3+} + 2 \text{I}^- \rightarrow \text{Fe}^{2+} + \text{I}_2 \] we will follow these steps: ### Step 1: Identify the half-reactions and their standard electrode potentials. - The reduction half-reaction for iron is: \[ \text{Fe}^{3+} + e^- \rightarrow \text{Fe}^{2+} \] with a standard electrode potential \( E^\circ = 0.771 \, \text{V} \). - The reduction half-reaction for iodine is: \[ \text{I}_2 + 2e^- \rightarrow 2 \text{I}^- \] with a standard electrode potential \( E^\circ = 0.536 \, \text{V} \). ### Step 2: Write the oxidation half-reaction for iodine. Since iodine is being oxidized in the overall reaction, we need to reverse the reduction half-reaction: \[ 2 \text{I}^- \rightarrow \text{I}_2 + 2e^- \] The standard electrode potential for this oxidation reaction will be the negative of the reduction potential: \[ E^\circ_{\text{oxidation}} = -0.536 \, \text{V} \] ### Step 3: Determine the cathode and anode reactions. - **Cathode (reduction)**: The reduction of \( \text{Fe}^{3+} \) to \( \text{Fe}^{2+} \) occurs at the cathode. - **Anode (oxidation)**: The oxidation of \( \text{I}^- \) to \( \text{I}_2 \) occurs at the anode. ### Step 4: Calculate the cell potential using the formula. The cell potential \( E_{cell} \) can be calculated using the formula: \[ E_{cell} = E^\circ_{\text{cathode}} - E^\circ_{\text{anode}} \] Substituting the values: \[ E_{cell} = 0.771 \, \text{V} - 0.536 \, \text{V} \] \[ E_{cell} = 0.235 \, \text{V} \] ### Conclusion The standard cell potential \( E_{cell} \) for the reaction is: \[ \boxed{0.235 \, \text{V}} \]

To find the cell potential \( E_{cell} \) for the reaction: \[ \text{Fe}^{3+} + 2 \text{I}^- \rightarrow \text{Fe}^{2+} + \text{I}_2 \] we will follow these steps: ### Step 1: Identify the half-reactions and their standard electrode potentials. - The reduction half-reaction for iron is: ...
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