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k=4.95xx10^(-5) S cm^(-1) for a 0.001 M ...

`k=4.95xx10^(-5) S cm^(-1)` for a `0.001 M `solution. The reciprocal of the degree of dissociation of acetic acid, if `wedge_(m)^(@)` for acetic acid is `400S cm^(-2) mol^(-1)` is `:`

A

7

B

8

C

9

D

10

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AI Generated Solution

The correct Answer is:
To solve the problem, we need to find the reciprocal of the degree of dissociation (α) of acetic acid given the conductivity (k) and the molar conductivity at infinite dilution (λ_m^0). ### Step-by-Step Solution: 1. **Given Data**: - Conductivity (k) = \(4.95 \times 10^{-5} \, \text{S cm}^{-1}\) - Concentration (C) = \(0.001 \, \text{M}\) - Molar conductivity at infinite dilution (λ_m^0) = \(400 \, \text{S cm}^2 \text{mol}^{-1}\) 2. **Calculate Molar Conductivity (λ_m)**: The molar conductivity (λ_m) at a given concentration can be calculated using the formula: \[ \lambda_m = \frac{1000 \cdot k}{C} \] Substituting the values: \[ \lambda_m = \frac{1000 \cdot (4.95 \times 10^{-5})}{0.001} \] \[ \lambda_m = \frac{4.95 \times 10^{-2}}{0.001} = 4.95 \times 10^{1} = 49.5 \, \text{S cm}^2 \text{mol}^{-1} \] 3. **Calculate Degree of Dissociation (α)**: The degree of dissociation (α) can be calculated using the formula: \[ \alpha = \frac{\lambda_m}{\lambda_m^0} \] Substituting the values: \[ \alpha = \frac{49.5}{400} \] 4. **Calculate the Reciprocal of Degree of Dissociation (1/α)**: To find the reciprocal of the degree of dissociation: \[ \frac{1}{\alpha} = \frac{\lambda_m^0}{\lambda_m} = \frac{400}{49.5} \] Performing the division: \[ \frac{1}{\alpha} \approx 8.08 \] 5. **Final Answer**: Rounding off, we find that the reciprocal of the degree of dissociation is approximately: \[ \frac{1}{\alpha} \approx 8 \] ### Conclusion: The reciprocal of the degree of dissociation of acetic acid is **8**.

To solve the problem, we need to find the reciprocal of the degree of dissociation (α) of acetic acid given the conductivity (k) and the molar conductivity at infinite dilution (λ_m^0). ### Step-by-Step Solution: 1. **Given Data**: - Conductivity (k) = \(4.95 \times 10^{-5} \, \text{S cm}^{-1}\) - Concentration (C) = \(0.001 \, \text{M}\) - Molar conductivity at infinite dilution (λ_m^0) = \(400 \, \text{S cm}^2 \text{mol}^{-1}\) ...
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