Home
Class 12
CHEMISTRY
If in a reaction A rarr Products, the co...

If in a reaction `A rarr` Products, the concentrations of reactant `A` are `c_(0), ac_(0), a^(2)c_(0) a^(3)c_(0)`, …after time interval `0,t,2t,3t`…. Where `a` is constant, given, `0 lt alt 1`, show that the reaction is of first order. Also calculate the relation in `k, a`, and `t`.

Text Solution

AI Generated Solution

To solve the problem, we need to show that the reaction is of first order and derive the relationship between the rate constant \( k \), the constant \( a \), and the time \( t \). ### Step-by-Step Solution: 1. **Understanding the Concentrations**: - At time \( t = 0 \), the concentration of \( A \) is \( c_0 \). - At time \( t = T \), the concentration is \( ac_0 \). - At time \( t = 2T \), the concentration is \( a^2c_0 \). ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Solved Example|52 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 4.1 (Objective)|9 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Analytical And Descriptive)|34 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|18 Videos

Similar Questions

Explore conceptually related problems

The ratio of t_(0.75) and t_(0.5) for first order reaction :-

In a first-order reaction A rarr B , if K is the rate constant and initial concentration of the reactant is 0.5 M , then half-life is

In a first order reaction, the concentrations of the reactant, 30 minutes and 40 minutes after the start are C_(1) and C_(2) ( in moles // litre ) respectively . What was C_(0) , initial concentration ?

The plot of In (c_(0))/(c_(0)-x) against t is a straight line, showing the reaction to be a

The order of reaction is an experimentally determined quanity. It may be zero, poistive, negative, or fractional. The kinetic equation of nth order reaction is k xx t = (1)/((n-1))[(1)/((a-x)^(n-1)) - (1)/(a^(n-1))] …(i) Half life of nth order reaction depends on the initial concentration according to the following relation: t_(1//2) prop (1)/(a^(n-1)) ...(ii) The unit of the rate constant varies with the order but general relation for the unit of nth order reaction is Units of k = [(1)/(Conc)]^(n-1) xx "Time"^(-1) ...(iii) The differential rate law for nth order reaction may be given as: (dX)/(dt) = k[A]^(n) ...(iv) where A denotes the reactant. The rate constant for zero order reaction is where c_(0) and c_(t) are concentration of reactants at respective times.

Kinetic energy of a charged particle is zero at time t_(0) . K at time 2 t_(0) . 2K at time 3 t_(0) . It remains constant (i.e.2K) upto 4 t_(0) . Choose the correct option.

For a first order reaction, time taken for half of the reaction to complete is t_(1)and 3/4 of the reaction to complete is t_(2) . How are t_(1)and t_(2) related?

Which of the following expresison is correct for first order reaction ( c_(0) refers to initial concentration of reactant)

For a certain reaction the variation of rate constant with temperature is given by the equation ln k_(t) = lnk_(0) + ((ln 3)t)/(10) (t ge 0^(@)C) The value of temperature coefficient of the reaction is

For a certain reaction the variation of rate constant with temperature is given by the equation ln k_(t) = lnk_(0) + ((ln 3)t)/(10) (t ge 0^(@)C) The value of temperature coefficient of the reaction is

CENGAGE CHEMISTRY ENGLISH-CHEMICAL KINETICS-Archives Subjective
  1. If in a reaction A rarr Products, the concentrations of reactant A are...

    Text Solution

    |

  2. Rate of a reaction A + B rarr Product, is given as a function of diffe...

    Text Solution

    |

  3. A first order reaction is 20% complete in 10 min. Calculate (a) the sp...

    Text Solution

    |

  4. While studying the decompoistion of gaseous N(2)O(5), it is observed t...

    Text Solution

    |

  5. A first order gas reaction has k = 1.5 xx 10^(-6) s^(-1) at 200^(@)C. ...

    Text Solution

    |

  6. A first order reaction is 50% complete in 30 minutes at 27^(@)C and in...

    Text Solution

    |

  7. In a Arrhenius equation for a certain reaction, the values of A and E(...

    Text Solution

    |

  8. The decomposition of N(2)O(5) according to the equation: 2N(2)O(5)(g) ...

    Text Solution

    |

  9. If the rate of decomposition of N 2 ​ O 5 ​ during a certain time...

    Text Solution

    |

  10. The gas phase decompoistion of dimethyl ether follows first order kine...

    Text Solution

    |

  11. A first order reaction A rarr B requires activation energy of 70 kJ mo...

    Text Solution

    |

  12. form the following data for the reaction between A and B, (a) Cal...

    Text Solution

    |

  13. At 380^(@)C, the half-life period for the first order decomposition of...

    Text Solution

    |

  14. The ionization constant of overset(o+)(NH(4)) ion in water is 5.6 xx 1...

    Text Solution

    |

  15. The time required for 10% completion of a first order reaction at 298K...

    Text Solution

    |

  16. The rate constant for the first order decomposition of H(2)O(2) is giv...

    Text Solution

    |

  17. For the equation N(2)O(5)(g)=2NO(2)(g)+(1//2)O(2)(g), calculate the ...

    Text Solution

    |

  18. The rate constant of a reaction is 1.5 xx 10^(7)s^(-1) at 50^(@)C and ...

    Text Solution

    |

  19. The rate constant for an isomerization reaction, A rarr B is 4.5 xx 10...

    Text Solution

    |

  20. An organic reaction is carried out at 500 K. If the same reaction carr...

    Text Solution

    |

  21. The vapour pressure of two miscible liquids (A) and (B) are 300mm of H...

    Text Solution

    |