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For the decompoistion of HI at 1000 K(2H...

For the decompoistion of `HI` at `1000 K(2HI rarr H_(2)+I_(2))`, following data were obtained:
`|{:([HI] (M),"Rate of decomposition of HI" (mol L^(-1) s^(-1))),(0.1,2.75 xx 10^(-8)),(0.2,11 xx 10^(-8)),(0.3,24.75 xx 10^(-8)):}|`
The order of reaction is

A

`1`

B

`2`

C

`0`

D

`1.5`

Text Solution

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The correct Answer is:
To determine the order of the reaction for the decomposition of HI at 1000 K, we will analyze the provided experimental data and apply the method of rate laws. ### Step-by-Step Solution: 1. **Write the Rate Law Expression**: The rate of the reaction can be expressed as: \[ \text{Rate} = k \cdot [HI]^n \] where \( k \) is the rate constant and \( n \) is the order of the reaction with respect to HI. 2. **Use Experimental Data**: We have the following data: - Experiment 1: \([HI] = 0.1 \, M\), Rate = \(2.75 \times 10^{-8} \, \text{mol L}^{-1} \text{s}^{-1}\) - Experiment 2: \([HI] = 0.2 \, M\), Rate = \(11 \times 10^{-8} \, \text{mol L}^{-1} \text{s}^{-1}\) - Experiment 3: \([HI] = 0.3 \, M\), Rate = \(24.75 \times 10^{-8} \, \text{mol L}^{-1} \text{s}^{-1}\) 3. **Set Up Ratios for Two Experiments**: We will compare the first and second experiments to find \( n \). \[ \frac{R_2}{R_1} = \frac{k \cdot [0.2]^n}{k \cdot [0.1]^n} \] This simplifies to: \[ \frac{R_2}{R_1} = \frac{[0.2]^n}{[0.1]^n} \] 4. **Substituting the Rates**: Substitute the rates from the experiments into the equation: \[ \frac{11 \times 10^{-8}}{2.75 \times 10^{-8}} = \frac{(0.2)^n}{(0.1)^n} \] Simplifying the left side: \[ 4 = \left(\frac{0.2}{0.1}\right)^n = (2)^n \] 5. **Solving for \( n \)**: From the equation \( 4 = 2^n \), we can see that: \[ n = 2 \] 6. **Conclusion**: The order of the reaction with respect to HI is 2. Thus, the rate law can be expressed as: \[ \text{Rate} = k \cdot [HI]^2 \] ### Final Answer: The order of the reaction is **2**.

To determine the order of the reaction for the decomposition of HI at 1000 K, we will analyze the provided experimental data and apply the method of rate laws. ### Step-by-Step Solution: 1. **Write the Rate Law Expression**: The rate of the reaction can be expressed as: \[ \text{Rate} = k \cdot [HI]^n ...
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