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The plot of In (c(0))/(c(0)-x) against t...

The plot of In `(c_(0))/(c_(0)-x)` against `t` is a straight line, showing the reaction to be a

A

Zero order reaction

B

First order reaction

C

Second order reaction

D

Half order reaction

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The correct Answer is:
To determine the order of the reaction based on the plot of \(\ln\left(\frac{c_0}{c_0 - x}\right)\) against \(t\), we can follow these steps: ### Step 1: Understand the Integrated Rate Law for First-Order Reactions For a first-order reaction, the integrated rate law can be expressed as: \[ \ln\left(\frac{[A]_0}{[A]}\right) = kt \] where \([A]_0\) is the initial concentration, \([A]\) is the concentration at time \(t\), and \(k\) is the rate constant. ### Step 2: Define Variables Let: - \(c_0\) = initial concentration of the reactant - \(x\) = amount of reactant that has reacted at time \(t\) - The concentration of the reactant at time \(t\) can be expressed as: \[ c = c_0 - x \] ### Step 3: Substitute into the Integrated Rate Law Substituting \(c_0\) and \(c\) into the integrated rate law gives: \[ \ln\left(\frac{c_0}{c_0 - x}\right) = kt \] ### Step 4: Analyze the Plot The equation \(\ln\left(\frac{c_0}{c_0 - x}\right) = kt\) indicates that if we plot \(\ln\left(\frac{c_0}{c_0 - x}\right)\) against time \(t\), we will obtain a straight line. The slope of this line will be equal to the rate constant \(k\). ### Step 5: Conclusion Since the plot of \(\ln\left(\frac{c_0}{c_0 - x}\right)\) against \(t\) is a straight line, this indicates that the reaction follows first-order kinetics. ### Final Answer The reaction is a **first-order reaction**. ---

To determine the order of the reaction based on the plot of \(\ln\left(\frac{c_0}{c_0 - x}\right)\) against \(t\), we can follow these steps: ### Step 1: Understand the Integrated Rate Law for First-Order Reactions For a first-order reaction, the integrated rate law can be expressed as: \[ \ln\left(\frac{[A]_0}{[A]}\right) = kt \] where \([A]_0\) is the initial concentration, \([A]\) is the concentration at time \(t\), and \(k\) is the rate constant. ...
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL KINETICS-Archives Subjective
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