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The first order reaction: Sucrose rarr...

The first order reaction:
Sucrose `rarr` Glucose + Fructose takes place at `308 K` in `0.5 N HCl`. At time zero the initial total rotation of the mixture is `32.4^(@)`. After `10 min`, the total rotation is `28.8^(@)`. If the rotation of sucrose per mole is `85^(@)`, that of glucose is `7.4^(@)`, and of fructose is `-86.04^(@)`, calculate the half life of the reaction.

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To solve the problem, we will follow these steps: ### Step 1: Determine the Initial Concentration of Sucrose We are given the initial total rotation of the mixture as \(32.4^\circ\) and the specific rotation of sucrose as \(85^\circ\). We can calculate the initial concentration of sucrose (\(A\)) using the formula: \[ A = \frac{\text{Initial Rotation}}{\text{Specific Rotation of Sucrose}} = \frac{32.4}{85} = 0.38 \, \text{moles} \] ...
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL KINETICS-Archives Subjective
  1. The first order reaction: Sucrose rarr Glucose + Fructose takes plac...

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  2. Rate of a reaction A + B rarr Product, is given as a function of diffe...

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  3. A first order reaction is 20% complete in 10 min. Calculate (a) the sp...

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  4. While studying the decompoistion of gaseous N(2)O(5), it is observed t...

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  5. A first order gas reaction has k = 1.5 xx 10^(-6) s^(-1) at 200^(@)C. ...

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  6. A first order reaction is 50% complete in 30 minutes at 27^(@)C and in...

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  7. In a Arrhenius equation for a certain reaction, the values of A and E(...

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  8. The decomposition of N(2)O(5) according to the equation: 2N(2)O(5)(g) ...

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  9. If the rate of decomposition of N 2 ​ O 5 ​ during a certain time...

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  10. The gas phase decompoistion of dimethyl ether follows first order kine...

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  11. A first order reaction A rarr B requires activation energy of 70 kJ mo...

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  12. form the following data for the reaction between A and B, (a) Cal...

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  13. At 380^(@)C, the half-life period for the first order decomposition of...

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  14. The ionization constant of overset(o+)(NH(4)) ion in water is 5.6 xx 1...

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  15. The time required for 10% completion of a first order reaction at 298K...

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  16. The rate constant for the first order decomposition of H(2)O(2) is giv...

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  17. For the equation N(2)O(5)(g)=2NO(2)(g)+(1//2)O(2)(g), calculate the ...

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  18. The rate constant of a reaction is 1.5 xx 10^(7)s^(-1) at 50^(@)C and ...

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  19. The rate constant for an isomerization reaction, A rarr B is 4.5 xx 10...

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  20. An organic reaction is carried out at 500 K. If the same reaction carr...

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  21. The vapour pressure of two miscible liquids (A) and (B) are 300mm of H...

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