Home
Class 12
CHEMISTRY
In chemical kinetics, only a small fract...

In chemical kinetics, only a small fraction of colliisons lead to reactions. This is because

A

The colliding molecuels may not be appropriately oriented to one another and the colliisons are not energetic.

B

The colliding molecuels are properly oriented to one another and the colliison are highly energetic.

C

The colliding molecules are properly oriented to one another and the colliisons are not highly enrgetic.

D

The colliding molecules may not be appropriately oriented to one another and the colliison are very enrgetic.

Text Solution

AI Generated Solution

The correct Answer is:
**Step-by-Step Solution:** 1. **Understanding Collision Theory**: - In chemical kinetics, the collision theory states that for a reaction to occur, reactant molecules must collide with each other. However, not all collisions result in a reaction. 2. **Effective Collisions**: - For a collision to be effective (i.e., lead to a reaction), two conditions must be met: - The colliding molecules must be properly oriented relative to each other. - The colliding molecules must possess sufficient energy to overcome the activation energy barrier. 3. **Orientation of Molecules**: - Proper orientation means that the molecules must align in a way that allows the necessary bonds to break and form. If the molecules collide in an incorrect orientation, the reaction will not occur, even if they have enough energy. 4. **Energy of Collisions**: - The energy of the colliding molecules must be greater than or equal to the activation energy required for the reaction. If the energy is too low, the molecules will not react, regardless of their orientation. 5. **Conclusion**: - Therefore, only a small fraction of collisions lead to reactions because many collisions do not meet the criteria of proper orientation and sufficient energy. This results in a low probability of successful reactions occurring. **Final Statement**: In summary, the reason why only a small fraction of collisions leads to reactions is that colliding molecules may not be properly oriented, and the collisions may not have sufficient energy to result in a reaction. ---

**Step-by-Step Solution:** 1. **Understanding Collision Theory**: - In chemical kinetics, the collision theory states that for a reaction to occur, reactant molecules must collide with each other. However, not all collisions result in a reaction. 2. **Effective Collisions**: - For a collision to be effective (i.e., lead to a reaction), two conditions must be met: - The colliding molecules must be properly oriented relative to each other. ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Solved Example|52 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 4.1 (Objective)|9 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Analytical And Descriptive)|34 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|18 Videos

Similar Questions

Explore conceptually related problems

Reaction of with RMgX lead to formation of

Reaction of with RMgX leads to formation of

A chemical reaction occurs as a result of colliisons between reacting molecules. Therefore, the reaction rate is given by

According to the colliison theory, most molecular colliisons do not lead to reaction. Which of the following is //are necessary for colliisons to successfully lead to reaction ?

which of the following leads to redox reaction ?

Heat at the rate of 200 W is produced in an X-ray tube operating at 20 kV. Find the current in the circuit. Assume that only a small fraction of the kinetic energy of electron is converted into X-rays.

Write the balanced chemical equation for each of the following reactions: Lead nitrate solution is added to sodium chloride solution.

Discuss on the kinetic spontaneity of a chemical reaction. Is a slow reaction spontaneous? Why?

Write a balanced chemical equation for the reaction Reaction of lead nitrate solution with ammonium hydroxide.

CENGAGE CHEMISTRY ENGLISH-CHEMICAL KINETICS-Archives Subjective
  1. In chemical kinetics, only a small fraction of colliisons lead to reac...

    Text Solution

    |

  2. Rate of a reaction A + B rarr Product, is given as a function of diffe...

    Text Solution

    |

  3. A first order reaction is 20% complete in 10 min. Calculate (a) the sp...

    Text Solution

    |

  4. While studying the decompoistion of gaseous N(2)O(5), it is observed t...

    Text Solution

    |

  5. A first order gas reaction has k = 1.5 xx 10^(-6) s^(-1) at 200^(@)C. ...

    Text Solution

    |

  6. A first order reaction is 50% complete in 30 minutes at 27^(@)C and in...

    Text Solution

    |

  7. In a Arrhenius equation for a certain reaction, the values of A and E(...

    Text Solution

    |

  8. The decomposition of N(2)O(5) according to the equation: 2N(2)O(5)(g) ...

    Text Solution

    |

  9. If the rate of decomposition of N 2 ​ O 5 ​ during a certain time...

    Text Solution

    |

  10. The gas phase decompoistion of dimethyl ether follows first order kine...

    Text Solution

    |

  11. A first order reaction A rarr B requires activation energy of 70 kJ mo...

    Text Solution

    |

  12. form the following data for the reaction between A and B, (a) Cal...

    Text Solution

    |

  13. At 380^(@)C, the half-life period for the first order decomposition of...

    Text Solution

    |

  14. The ionization constant of overset(o+)(NH(4)) ion in water is 5.6 xx 1...

    Text Solution

    |

  15. The time required for 10% completion of a first order reaction at 298K...

    Text Solution

    |

  16. The rate constant for the first order decomposition of H(2)O(2) is giv...

    Text Solution

    |

  17. For the equation N(2)O(5)(g)=2NO(2)(g)+(1//2)O(2)(g), calculate the ...

    Text Solution

    |

  18. The rate constant of a reaction is 1.5 xx 10^(7)s^(-1) at 50^(@)C and ...

    Text Solution

    |

  19. The rate constant for an isomerization reaction, A rarr B is 4.5 xx 10...

    Text Solution

    |

  20. An organic reaction is carried out at 500 K. If the same reaction carr...

    Text Solution

    |

  21. The vapour pressure of two miscible liquids (A) and (B) are 300mm of H...

    Text Solution

    |