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Analyze the generalized rate data: RX ...

Analyze the generalized rate data:
`RX + M^(ɵ) rarr` Product
`|{:("Experiment",[RX] "Substrate",[M^(ɵ)] "Attaking species","Rate"),(I,0.10 M,0.10 M,1.2 xx 10^(-4)),(II,0.20 M,0.10 M,2.4 xx 10^(-4)),(III,0.10 M,0.20 M,2.4 xx 10^(-4)),(IV,0.20 M,0.20 M,4.8 xx 10^(-4)):}|`
The value of rate constant for the give experiment data is

A

`1.2 xx 10^(-2)`

B

`1.2 xx 10^(-4)`

C

`1.2 xx 10^(-3)`

D

`2.4 xx 10^(-3)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given experimental data and determine the rate constant (k) for the reaction \( RX + M^{-} \rightarrow \text{Product} \). We will follow these steps: ### Step 1: Write the Rate Law The rate law for the reaction can be expressed as: \[ \text{Rate} = k [RX]^x [M^{-}]^y \] where \( x \) and \( y \) are the orders of the reaction with respect to \( RX \) and \( M^{-} \), respectively. ### Step 2: Determine the Order with Respect to \( RX \) We will compare the rates of Experiment I and Experiment II to find the value of \( x \). From the data: - Experiment I: \([RX] = 0.10 \, M\), \([M^{-}] = 0.10 \, M\), Rate = \(1.2 \times 10^{-4}\) - Experiment II: \([RX] = 0.20 \, M\), \([M^{-}] = 0.10 \, M\), Rate = \(2.4 \times 10^{-4}\) Using the rate law: \[ \frac{\text{Rate}_I}{\text{Rate}_{II}} = \frac{k [0.10]^x [0.10]^y}{k [0.20]^x [0.10]^y} \] This simplifies to: \[ \frac{1.2 \times 10^{-4}}{2.4 \times 10^{-4}} = \frac{[0.10]^x}{[0.20]^x} \] \[ \frac{1}{2} = \left(\frac{0.10}{0.20}\right)^x \] \[ \frac{1}{2} = \left(\frac{1}{2}\right)^x \] From this, we find that \( x = 1 \). ### Step 3: Determine the Order with Respect to \( M^{-} \) Next, we will compare the rates of Experiment I and Experiment III to find the value of \( y \). From the data: - Experiment I: Rate = \(1.2 \times 10^{-4}\) - Experiment III: \([RX] = 0.10 \, M\), \([M^{-}] = 0.20 \, M\), Rate = \(2.4 \times 10^{-4}\) Using the rate law: \[ \frac{\text{Rate}_I}{\text{Rate}_{III}} = \frac{k [0.10]^x [0.10]^y}{k [0.10]^x [0.20]^y} \] This simplifies to: \[ \frac{1.2 \times 10^{-4}}{2.4 \times 10^{-4}} = \frac{[0.10]^y}{[0.20]^y} \] \[ \frac{1}{2} = \left(\frac{0.10}{0.20}\right)^y \] \[ \frac{1}{2} = \left(\frac{1}{2}\right)^y \] From this, we find that \( y = 1 \). ### Step 4: Write the Final Rate Law Now that we have determined the orders, we can write the rate law: \[ \text{Rate} = k [RX]^1 [M^{-}]^1 = k [RX] [M^{-}] \] ### Step 5: Calculate the Rate Constant \( k \) We can use any of the experiments to find \( k \). Let's use Experiment I: \[ 1.2 \times 10^{-4} = k (0.10)(0.10) \] \[ 1.2 \times 10^{-4} = k (0.01) \] \[ k = \frac{1.2 \times 10^{-4}}{0.01} = 1.2 \times 10^{-2} \, \text{L mol}^{-1} \text{s}^{-1} \] ### Final Answer The value of the rate constant \( k \) is: \[ \boxed{1.2 \times 10^{-2} \, \text{L mol}^{-1} \text{s}^{-1}} \]

To solve the problem, we need to analyze the given experimental data and determine the rate constant (k) for the reaction \( RX + M^{-} \rightarrow \text{Product} \). We will follow these steps: ### Step 1: Write the Rate Law The rate law for the reaction can be expressed as: \[ \text{Rate} = k [RX]^x [M^{-}]^y \] where \( x \) and \( y \) are the orders of the reaction with respect to \( RX \) and \( M^{-} \), respectively. ...
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