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A reaction is 10% complete in 5min and 5...

A reaction is `10%` complete in `5min` and `50%` complete in `25 min`. Which of the following is/are correct?

A

a. Order of reaction is one.

B

b. Order of reaction is zero.

C

c. Reaction will be complete in finite time.

D

d. Reaction will be complete in infinite time.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the completion percentages of the reaction over time and determine the order of the reaction based on the given data. ### Step-by-Step Solution: 1. **Understanding the Data**: - The reaction is 10% complete in 5 minutes. - The reaction is 50% complete in 25 minutes. 2. **Calculating Completion Rates**: - From 0% to 10% completion takes 5 minutes. - From 10% to 50% completion takes an additional 20 minutes (from 5 minutes to 25 minutes). - This indicates that as the reaction progresses, the time taken for each percentage of completion is increasing. 3. **Identifying the Reaction Order**: - For a zero-order reaction, the rate of reaction is constant, and the time taken for completion is directly proportional to the extent of the reaction. - In this case, if we observe that the time taken increases linearly with the percentage completion (5 minutes for 10% and 25 minutes for 50%), it suggests that the rate of reaction is constant, which is characteristic of a zero-order reaction. 4. **Conclusion about the Reaction**: - Since the time taken for the reaction to reach 50% completion is five times that for 10% completion, it indicates that the reaction does not depend on the concentration of the reactants, confirming that it is a zero-order reaction. 5. **Finite Time for Completion**: - In a zero-order reaction, the reaction will eventually reach completion in a finite amount of time. Therefore, it can be concluded that the reaction will complete in finite time. ### Final Answer: Based on the analysis, the correct options are: - Option B: The order of the reaction is zero. - Option C: The reaction will complete in finite time.
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