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Conisder the reaction represented by the...

Conisder the reaction represented by the equation:
`CH_(3)Cl(g) + H_(2)O(g) rarr CH_(3)OH(g) + HCl(g)`
These kinetics data were obtained for the given reaction concentrations:
`{:("Initial conc (M)",,"Initial rate of disappearance"),([CH_(3)Cl],[H_(2)O],"of "CH_(3)Cl(Ms^(-1))),(0.2,0.2,1),(0.4,0.2,2),(0.4,0.4,8):}`
Order with respect to `[CH_(3)Cl]` will be

A

`0`

B

`1`

C

`2`

D

`3`

Text Solution

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The correct Answer is:
To determine the order of the reaction with respect to \([CH_3Cl]\), we will analyze the provided kinetic data using the rate law expression. ### Step-by-Step Solution: 1. **Write the Rate Law Expression**: The rate law for the reaction can be expressed as: \[ \text{Rate} = k [CH_3Cl]^x [H_2O]^y \] where \(x\) is the order with respect to \([CH_3Cl]\) and \(y\) is the order with respect to \([H_2O]\). 2. **Select Two Experiments**: We will use the data from the first two experiments to find \(x\). The data is: - Experiment 1: \([CH_3Cl] = 0.2\, M\), \([H_2O] = 0.2\, M\), Rate = 1 \(Ms^{-1}\) - Experiment 2: \([CH_3Cl] = 0.4\, M\), \([H_2O] = 0.2\, M\), Rate = 2 \(Ms^{-1}\) 3. **Set Up the Rate Ratio**: We can set up the ratio of the rates from the two experiments: \[ \frac{\text{Rate}_1}{\text{Rate}_2} = \frac{k [CH_3Cl]_1^x [H_2O]_1^y}{k [CH_3Cl]_2^x [H_2O]_2^y} \] Substituting the values: \[ \frac{1}{2} = \frac{(0.2)^x (0.2)^y}{(0.4)^x (0.2)^y} \] 4. **Simplify the Equation**: The \([H_2O]^y\) terms will cancel out: \[ \frac{1}{2} = \frac{(0.2)^x}{(0.4)^x} \] This can be rewritten as: \[ \frac{1}{2} = \left(\frac{0.2}{0.4}\right)^x \] Since \(\frac{0.2}{0.4} = \frac{1}{2}\), we have: \[ \frac{1}{2} = \left(\frac{1}{2}\right)^x \] 5. **Equate the Exponents**: Since the bases are the same, we can equate the exponents: \[ 1 = x \] 6. **Conclusion**: Therefore, the order with respect to \([CH_3Cl]\) is: \[ x = 1 \] ### Final Answer: The order with respect to \([CH_3Cl]\) is **1**.

To determine the order of the reaction with respect to \([CH_3Cl]\), we will analyze the provided kinetic data using the rate law expression. ### Step-by-Step Solution: 1. **Write the Rate Law Expression**: The rate law for the reaction can be expressed as: \[ \text{Rate} = k [CH_3Cl]^x [H_2O]^y ...
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