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When the rate determined by the change i...

When the rate determined by the change in concentration of two different reactants, then the kinetic equation may be expressed as

A

`k_(2) = (2.303)/((a-b)t)log.((a-x)b)/((b-x)a)`

B

`k_(2) = (2.303)/((a-b)t)log.((a-x))/((b+x))`

C

`k_(2) = (2.303)/((a-b)t)log.((a-x))/((b-x))`

D

`k_(2) = (1)/(t) xx (x)/((a-x))`

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To solve the question regarding the kinetic equation when the rate is determined by the change in concentration of two different reactants, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction**: Consider the reaction: \[ A + B \rightarrow \text{Products} \] Here, \( A \) and \( B \) are the two different reactants. 2. **Define Initial Concentrations**: At time \( t = 0 \): - Concentration of \( A \) = \( [A]_0 = A \) - Concentration of \( B \) = \( [B]_0 = B \) - Concentration of products = 0 3. **Define Concentrations at Time \( t \)**: At time \( t \): - Concentration of \( A \) = \( [A] = A - x \) - Concentration of \( B \) = \( [B] = B - x \) - Concentration of products = \( x \) 4. **Write the Rate Equation**: The rate of the reaction can be expressed as: \[ \text{Rate} = -\frac{d[A]}{dt} = -\frac{d[B]}{dt} = k [A][B] \] Substituting the expressions for \( [A] \) and \( [B] \): \[ \text{Rate} = k (A - x)(B - x) \] 5. **Integrate the Rate Equation**: We can express the rate as: \[ \frac{dx}{dt} = k (A - x)(B - x) \] Rearranging gives: \[ \frac{dx}{(A - x)(B - x)} = k dt \] 6. **Set Up the Integral**: Integrate both sides: \[ \int_0^x \frac{dx}{(A - x)(B - x)} = \int_0^t k dt \] 7. **Perform the Integration**: The left side can be integrated using partial fractions: \[ \frac{1}{(A - x)(B - x)} = \frac{1}{B - A} \left( \frac{1}{A - x} - \frac{1}{B - x} \right) \] Thus, the integral becomes: \[ \frac{1}{B - A} \left( \ln|A - x| - \ln|B - x| \right) \bigg|_0^x = kt \] 8. **Evaluate the Limits**: Evaluating the limits gives: \[ \frac{1}{B - A} \left( \ln|A - x| - \ln|B - x| - (\ln|A| - \ln|B|) \right) = kt \] 9. **Rearranging the Equation**: This can be rearranged to find: \[ kt = \frac{1}{B - A} \left( \ln\left(\frac{(A - x)}{(B - x)}\right) + \ln\left(\frac{B}{A}\right) \right) \] 10. **Final Expression**: The final expression can be simplified to: \[ k = \frac{2.303}{B - A} \cdot \frac{t}{\log\left(\frac{(A - x)}{(B - x)}\right)} \]

To solve the question regarding the kinetic equation when the rate is determined by the change in concentration of two different reactants, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reaction**: Consider the reaction: \[ A + B \rightarrow \text{Products} ...
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