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The wrong statement is...

The wrong statement is

A

All the colliisons between reactant molecules do not lead to a chemical change.

B

A zero order reaction proceeds at a constant rate independent of concentration or time.

C

Fast reactions have low activation energies.

D

In a first order reaction, the reaction ideally takes finite time to be complete.

Text Solution

AI Generated Solution

The correct Answer is:
To determine the wrong statement from the given options regarding chemical kinetics, we will analyze each statement one by one. ### Step 1: Analyze Option A **Statement:** All the collisions between reactant molecules do not lead to a chemical change. **Explanation:** This statement is true. Not all collisions between reactant molecules result in a reaction. For a reaction to occur, the colliding molecules must have sufficient energy (known as threshold energy) and proper orientation. Therefore, this option is correct. ### Step 2: Analyze Option B **Statement:** A zero-order reaction proceeds at a constant rate independent of concentration or time. **Explanation:** This statement is also true. In a zero-order reaction, the rate of reaction is constant and does not depend on the concentration of the reactants. The rate law for a zero-order reaction can be expressed as Rate = k, where k is the rate constant. Therefore, this option is correct. ### Step 3: Analyze Option C **Statement:** Fast reactions have low activation energies. **Explanation:** This statement is true. Fast reactions typically have low activation energies, meaning that a greater number of molecules have sufficient energy to overcome the energy barrier for the reaction to occur. Therefore, this option is correct. ### Step 4: Analyze Option D **Statement:** In a first-order reaction, the reaction ideally takes finite time to complete. **Explanation:** This statement is false. First-order reactions do not complete in a finite amount of time; they asymptotically approach completion. This means that theoretically, they take an infinite amount of time to reach completion. Therefore, this option is incorrect. ### Conclusion The wrong statement among the options provided is **Option D**. ---
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL KINETICS-Exercises Single Correct
  1. t(1//2) = constant confirms the first order of the reaction as one a^(...

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  2. Collision theory is applicable to

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  3. The wrong statement is

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  4. Which of the following will react at the highest rate ?

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  5. For a reaction, the rate constant is expressed as k = Ae^(-40000//T). ...

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  6. A reaction takes place in theee steps: the rate constant are k(1), k(2...

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  7. A reaction rate constant is given by k = 1.2 xx 10^(14) e^((-2500)/(...

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  8. For the reaction 2NO(g) + H(2)(g) rarr N(2)O(g) + H(2)O(g), at 900 K f...

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  9. An exothermic reaction ArarrB has an activation energy of 17 kJ per mo...

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  10. k(34^(@)):k(35^(@)) lt 1, then

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  11. The compoistion of N(2)O(5) is a first order reaction represented by: ...

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  12. A catalyst only

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  13. The free energy change the due to a reaction is zero when

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  14. What is Delta H for the reaction A + B rarr C where the mechanism invo...

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  15. What can you say about the existence of A if the potential energy dia...

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  16. In a multistep reaction such as A + B rarr Q rarr C. The potential en...

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  17. In which statement is true ?

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  18. Given the following two mechanisms, one with catalyst and the other wi...

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  19. The mechanism for the overall reaction is A(2) + B rarr C A(2) r...

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  20. Which of the following statement is correct

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