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For the reaction 2NO(g) + H(2)(g) rarr N...

For the reaction `2NO(g) + H_(2)(g) rarr N_(2)O(g) + H_(2)O(g)`, at `900 K` following data are observed.
`{:("Initial pressure of NO (atm)","Initial pressure of" H_(2)o (atm),"Initial rate of pressure decrease" (atm min^(-1))),(0.150,0.40,0.020),(0.075,0.40,0.005),(0.150,0.20,0.010):}`
Find the order of reaction.

A

`3`

B

`2`

C

`1`

D

`0`

Text Solution

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The correct Answer is:
To find the order of the reaction for the given reaction \(2NO(g) + H_2(g) \rightarrow N_2O(g) + H_2O(g)\) at \(900 K\), we will use the initial rate method based on the provided experimental data. ### Step-by-Step Solution: 1. **Write the Rate Law Expression:** The rate law for the reaction can be expressed as: \[ \text{Rate} = k [NO]^x [H_2]^y \] where \(x\) is the order with respect to \(NO\) and \(y\) is the order with respect to \(H_2\). 2. **Use the First Two Experiments to Find \(x\):** From the data: - Experiment 1: \(P_{NO} = 0.150 \, \text{atm}, P_{H_2} = 0.40 \, \text{atm}, \text{Rate} = 0.020 \, \text{atm min}^{-1}\) - Experiment 2: \(P_{NO} = 0.075 \, \text{atm}, P_{H_2} = 0.40 \, \text{atm}, \text{Rate} = 0.005 \, \text{atm min}^{-1}\) Set up the ratio of the rates: \[ \frac{0.020}{0.005} = \frac{k (0.150)^x (0.40)^y}{k (0.075)^x (0.40)^y} \] This simplifies to: \[ 4 = \left(\frac{0.150}{0.075}\right)^x \] \[ 4 = 2^x \] Solving for \(x\): \[ x = 2 \] 3. **Use the First and Third Experiments to Find \(y\):** From the data: - Experiment 1: \(P_{NO} = 0.150 \, \text{atm}, P_{H_2} = 0.40 \, \text{atm}, \text{Rate} = 0.020 \, \text{atm min}^{-1}\) - Experiment 3: \(P_{NO} = 0.150 \, \text{atm}, P_{H_2} = 0.20 \, \text{atm}, \text{Rate} = 0.010 \, \text{atm min}^{-1}\) Set up the ratio of the rates: \[ \frac{0.020}{0.010} = \frac{k (0.150)^x (0.40)^y}{k (0.150)^x (0.20)^y} \] This simplifies to: \[ 2 = \left(\frac{0.40}{0.20}\right)^y \] \[ 2 = 2^y \] Solving for \(y\): \[ y = 1 \] 4. **Calculate the Total Order of the Reaction:** The total order of the reaction is given by: \[ \text{Total Order} = x + y = 2 + 1 = 3 \] ### Final Answer: The order of the reaction is **3**.

To find the order of the reaction for the given reaction \(2NO(g) + H_2(g) \rightarrow N_2O(g) + H_2O(g)\) at \(900 K\), we will use the initial rate method based on the provided experimental data. ### Step-by-Step Solution: 1. **Write the Rate Law Expression:** The rate law for the reaction can be expressed as: \[ \text{Rate} = k [NO]^x [H_2]^y ...
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