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For which of the following represents th...

For which of the following represents the expresison for theee/fourth life reaction?

A

`k/2.303 log4//3`

B

`2.303/k log 3//4`

C

`2.303/k log 4`

D

`2.303/k log 3`

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The correct Answer is:
To solve the question regarding the expression for the three-fourth life of a reaction, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Concept of Half-Life and Three-Fourth Life:** - The half-life of a reaction is the time required for the concentration of a reactant to decrease to half of its initial concentration. - The three-fourth life (or 75% life) is the time required for the concentration of a reactant to decrease to one-fourth of its initial concentration. 2. **Identify the Reaction Order:** - The question implies that we are dealing with a first-order reaction. For a first-order reaction, the rate constant \( k \) is related to the concentration of the reactants. 3. **Use the First-Order Reaction Formula:** - The formula for the time \( t \) for a first-order reaction is given by: \[ t = \frac{2.303}{k} \log \left( \frac{[A_0]}{[A]} \right) \] where \( [A_0] \) is the initial concentration and \( [A] \) is the concentration at time \( t \). 4. **Determine the Concentration After Three-Fourths of the Reaction:** - If 75% of the reactant has reacted, then 25% remains. Therefore, if the initial concentration is \( [A_0] \), the final concentration \( [A] \) after 75% of the reaction will be: \[ [A] = [A_0] - 0.75[A_0] = 0.25[A_0] = \frac{[A_0]}{4} \] 5. **Substitute the Values into the Formula:** - Now substituting \( [A_0] \) and \( [A] \) into the formula: \[ t_{3/4} = \frac{2.303}{k} \log \left( \frac{[A_0]}{\frac{[A_0]}{4}} \right) \] - This simplifies to: \[ t_{3/4} = \frac{2.303}{k} \log \left( 4 \right) \] 6. **Final Expression:** - Therefore, the expression for the three-fourth life of a first-order reaction is: \[ t_{3/4} = \frac{2.303}{k} \log(4) \] - This corresponds to option number C in the question. ### Final Answer: The expression for the three-fourth life of the reaction is: \[ t_{3/4} = \frac{2.303}{k} \log(4) \] This is option C.

To solve the question regarding the expression for the three-fourth life of a reaction, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Concept of Half-Life and Three-Fourth Life:** - The half-life of a reaction is the time required for the concentration of a reactant to decrease to half of its initial concentration. - The three-fourth life (or 75% life) is the time required for the concentration of a reactant to decrease to one-fourth of its initial concentration. ...
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