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In the formation of sulphur trioxide by ...

In the formation of sulphur trioxide by the contact process,
`2SO_(2)(g)+O_(2)(g) hArr 2SO_(3)(g)`
The rate of reaction is expressed as
`-(d(O_2))/(dt) = 2.5 xx 10^(-4) mol L^(-1) s^(-1)`
The rate of disappearance of `(SO_(2))` will be

A

`5.0 xx 10^(-4) mol L^(-1) s^(-1)`

B

`-2.25 xx 10^(-4) mol L^(-1) s^(-1)`

C

`3.75 xx 10^(-4) mol L^(-1) s^(-1)`

D

`50.0 xx 10^(-4) mol L^(-1) s^(-1)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the rate of disappearance of \( SO_2 \) based on the given rate of disappearance of \( O_2 \) in the reaction: \[ 2SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g) \] ### Step-by-Step Solution: 1. **Identify the Rate of Reaction**: The rate of reaction can be expressed in terms of the change in concentration of the reactants and products. The rate of disappearance of \( O_2 \) is given as: \[ -\frac{d[O_2]}{dt} = 2.5 \times 10^{-4} \, \text{mol L}^{-1} \text{s}^{-1} \] 2. **Relate the Rates Using Stoichiometry**: From the balanced chemical equation, we can see that the stoichiometric coefficients are: - For \( SO_2 \): 2 - For \( O_2 \): 1 The relationship between the rates of disappearance of \( SO_2 \) and \( O_2 \) can be established using their stoichiometric coefficients: \[ -\frac{1}{2} \frac{d[SO_2]}{dt} = -\frac{1}{1} \frac{d[O_2]}{dt} \] 3. **Express the Rate of Disappearance of \( SO_2 \)**: Rearranging the equation gives us: \[ \frac{d[SO_2]}{dt} = 2 \frac{d[O_2]}{dt} \] 4. **Substituting the Given Rate**: Now, substitute the value of \( \frac{d[O_2]}{dt} \): \[ \frac{d[SO_2]}{dt} = 2 \times 2.5 \times 10^{-4} \, \text{mol L}^{-1} \text{s}^{-1} \] 5. **Calculate the Rate**: Performing the multiplication: \[ \frac{d[SO_2]}{dt} = 5.0 \times 10^{-4} \, \text{mol L}^{-1} \text{s}^{-1} \] Thus, the rate of disappearance of \( SO_2 \) is: \[ \frac{d[SO_2]}{dt} = 5.0 \times 10^{-4} \, \text{mol L}^{-1} \text{s}^{-1} \] ### Final Answer: The rate of disappearance of \( SO_2 \) is \( 5.0 \times 10^{-4} \, \text{mol L}^{-1} \text{s}^{-1} \).

To solve the problem, we need to determine the rate of disappearance of \( SO_2 \) based on the given rate of disappearance of \( O_2 \) in the reaction: \[ 2SO_2(g) + O_2(g) \rightleftharpoons 2SO_3(g) \] ### Step-by-Step Solution: ...
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