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Assertion (A) : The molecularity of the ...

Assertion (A) : The molecularity of the reaction
`H_(2) + Br_(2) rarr 2HBr` is `2`.
Reason (R ): The order of the reaction is `3//2`.

A

If both `(A)` and `(R )` are correct, and `(R )` is the correct explnation of `(A)`.

B

If both `(A)` and `(R )` are correct, but `(R )` is noth the correct explanation of `(A)`.

C

If `(A)` is correct, but `(R )` is incorrect.

D

If `(A)` is incorrect, but `(R )` is correct.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding Molecularity**: - Molecularity refers to the number of reactant molecules that collide in an elementary reaction step. - For the reaction \( H_2 + Br_2 \rightarrow 2HBr \), there are two reactants: one molecule of \( H_2 \) and one molecule of \( Br_2 \). - Therefore, the molecularity of this reaction is \( 1 + 1 = 2 \). 2. **Understanding Order of Reaction**: - The order of a reaction is the sum of the powers to which the concentration terms are raised in the rate law expression. - The rate law for the reaction can be expressed as: \[ \text{Rate} = k [H_2]^x [Br_2]^y \] - The order of the reaction is given as \( x + y \). 3. **Evaluating the Reason**: - The reason states that the order of the reaction is \( \frac{3}{2} \) (or \( 1.5 \)). - This implies that \( x + y = \frac{3}{2} \). - However, the order of a reaction must be determined experimentally and cannot be deduced solely from the stoichiometry of the balanced equation. 4. **Conclusion**: - The assertion (A) is correct: the molecularity of the reaction is indeed 2. - The reason (R) is also correct: the order of the reaction can be stated as \( \frac{3}{2} \), but it does not explain the assertion. - Therefore, the correct answer is that both A and R are correct, but R is not the correct explanation of A. ### Final Answer: - Assertion (A) is true. - Reason (R) is true but does not explain A. - Hence, the answer is: Both A and R are correct, but R is not the correct explanation of A.

To solve the question, we need to analyze both the assertion and the reason provided. ### Step-by-Step Solution: 1. **Understanding Molecularity**: - Molecularity refers to the number of reactant molecules that collide in an elementary reaction step. - For the reaction \( H_2 + Br_2 \rightarrow 2HBr \), there are two reactants: one molecule of \( H_2 \) and one molecule of \( Br_2 \). - Therefore, the molecularity of this reaction is \( 1 + 1 = 2 \). ...
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