Home
Class 12
CHEMISTRY
Assertion (A) : The order of the reactio...

Assertion (A) : The order of the reaction,
`CH_(3)COOC_(2)H_(5) + H_(2)O hArr CH_(3)COOH + C_(2)H_(5)OH`
is `2`. Reason (R ): The molecularity of this reaction is `2`.

A

If both `(A)` and `(R )` are correct, and `(R )` is the correct explnation of `(A)`.

B

If both `(A)` and `(R )` are correct, but `(R )` is noth the correct explanation of `(A)`.

C

If `(A)` is correct, but `(R )` is incorrect.

D

If `(A)` is incorrect, but `(R )` is correct.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understanding the Reaction The reaction given is: \[ CH_3COOC_2H_5 + H_2O \rightleftharpoons CH_3COOH + C_2H_5OH \] This is a hydrolysis reaction where an ester reacts with water to form an acid and an alcohol. ### Step 2: Determining the Order of the Reaction The order of a reaction is determined by how the rate of the reaction depends on the concentration of the reactants. In this case, since water is present in excess, its concentration remains relatively constant throughout the reaction. Therefore, the rate of the reaction primarily depends on the concentration of the ester \( CH_3COOC_2H_5 \). Given that the rate of reaction can be expressed as: \[ \text{Rate} = k [CH_3COOC_2H_5] \] This indicates that the reaction behaves as a first-order reaction with respect to the ester. Thus, the overall order of the reaction is 1, not 2. ### Step 3: Understanding Molecularity Molecularity refers to the number of reactant particles that collide to form products in a single step of a reaction. In this case, there are two reactants involved: 1. \( CH_3COOC_2H_5 \) (the ester) 2. \( H_2O \) (water) Since both of these reactants are involved in the rate-determining step, the molecularity of the reaction is: \[ 1 + 1 = 2 \] ### Conclusion - Assertion (A): The order of the reaction is 2. **(Incorrect)** - Reason (R): The molecularity of this reaction is 2. **(Correct)** Thus, the correct conclusion is that the assertion is incorrect, while the reason is correct. ### Final Answer The correct option is that Assertion (A) is incorrect and Reason (R) is correct. ---

To solve the question, we need to analyze both the assertion and the reason provided. ### Step 1: Understanding the Reaction The reaction given is: \[ CH_3COOC_2H_5 + H_2O \rightleftharpoons CH_3COOH + C_2H_5OH \] This is a hydrolysis reaction where an ester reacts with water to form an acid and an alcohol. ### Step 2: Determining the Order of the Reaction ...
Promotional Banner

Topper's Solved these Questions

  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Integer|15 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Fill In The Blanks|37 Videos
  • CHEMICAL KINETICS

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Single Correct|177 Videos
  • CARBOXYLIC ACIDS AND THEIR DERIVATIVES

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Analytical And Descriptive)|34 Videos
  • COORDINATION COMPOUNDS

    CENGAGE CHEMISTRY ENGLISH|Exercise Archives Subjective|18 Videos

Similar Questions

Explore conceptually related problems

The hydrolysis of ethyl acetate is a reaction of : CH_(3)COOC_(2)H_(5)+H_(2)Ooverset(H^(+))rarr CH_(3)COOH+C_(2)H_(5)OH

The equilibrium constant for the reaction CH_(3)COOH+C_(2)H_(5)OH hArr CH_(3)COOC_(2)H_(5)+H_(2)O is 4.0 at 25^(@)C . Calculate the weight of ethyl acetate that will be obtained when 120g of acetic acid are reacted with 92 g of alcohol.

Assertion : The major product formed by heating C_(6)H_(5)CH_(2)OC_(2)H_(5) with HI are C_(6)H_(5)CH_(2)I and C_(2)H_(5)OH. Reason : Benzyl cation is more stale than ethyl cation.

The rate of the reaction: CH_(3)COOC_(2)H_(5) + NaOH to Ch_(3)COONa + C_(2)H_(5) OH is given by the equation, rate = k [CH_(3) COOC_(2)H_(5)][NaOH] If concenration is expressed in mol/L the units of k are

CH_(3)COOC_(2)H_(5)(aq)+H_(2)O(l)overset(H^(+)(aq))toCH_(3)COOH(aq)+C_(2)H_(5)OH(aq) . What type of reaction is this?

Following reaction: (CH_(3))_(3)C-Br +H_(2)O rarr (CH_(3))_(3)C-OH +HBr is an example of -

The equilibrium constant for the reaction: CH_(3)COOH(l) +C_(2)H_(5)OH(l) hArr CH_(3)COOC_(2)H_(5)(l)+H_(2)O(l) has been found to be equal to 4 at 25^(@)C . Calculate the free energy change for the reaction.

CENGAGE CHEMISTRY ENGLISH-CHEMICAL KINETICS-Exercises Assertion-Reasoning
  1. Assertion (A): Hydrolyiss of ethyl acetate in the presence of acid is ...

    Text Solution

    |

  2. Assertion (A): Poistive catalyst lowers the activation energy of the r...

    Text Solution

    |

  3. Assertion (A) : The molecularity of the reaction H(2) + Br(2) rarr 2...

    Text Solution

    |

  4. Assertion (A): For the reaction RCl + NaOH(g) rarr ROH + NaCl, the r...

    Text Solution

    |

  5. According to the tranistion state theory, for the formation of on acti...

    Text Solution

    |

  6. Assertion (A) : The order of a reaction can be fractional but molecula...

    Text Solution

    |

  7. Assertion (A) : Both H(2)(g)+Cl(2)(g) rarr 2HCl(g) and H(2)(g)+Br(2)(g...

    Text Solution

    |

  8. Assertion (A) : In the reaction, N(2)+3H(2) rarr 2NH(3), the rate of r...

    Text Solution

    |

  9. Assertion (A) : Poistive catalysts increase the rate of reaction. Re...

    Text Solution

    |

  10. Assertion (A) : k=Ae^(-E(a)//RT), the Arrhenius equation represents th...

    Text Solution

    |

  11. Assertion (A) : If the activation energy of a reaction is zero, temper...

    Text Solution

    |

  12. Assertion (A) : An order with respect to any reactant or Product can b...

    Text Solution

    |

  13. Assertion (A) : Formation of HI is a bimolecular reaction. Reason (R...

    Text Solution

    |

  14. Assertion (A) : The order of the reaction, CH(3)COOC(2)H(5) + H(2)O ...

    Text Solution

    |

  15. Assertion (A) : For: aA+bB rarr Product. The order of reaction is equa...

    Text Solution

    |

  16. Assertion (A) : The rate constant of a pseudo unimolecular reaction ha...

    Text Solution

    |

  17. Assertion (A) : The rate constant of a zero order reaction has same un...

    Text Solution

    |

  18. Assertion (A) : k=Ae^(-E(a)//RT), the Arrhenius equation represents th...

    Text Solution

    |

  19. Assertion (A) : The rate of a chemical reaction whether exothermic or ...

    Text Solution

    |

  20. Assertion (A) : For a first order, the concentration of a reaction dec...

    Text Solution

    |