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For a first order reaction, the half-lif...

For a first order reaction, the half-life periof is `0.263 k`.
T or F

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To determine whether the statement "For a first-order reaction, the half-life period is 0.263 k" is true or false, we need to analyze the relationship between the half-life and the rate constant for a first-order reaction. ### Step-by-Step Solution: 1. **Understanding Half-Life for First-Order Reactions**: The half-life (t₁/₂) of a first-order reaction is defined as the time required for the concentration of a reactant to decrease to half of its initial concentration. 2. **Formula for Half-Life**: The formula for the half-life of a first-order reaction is given by: \[ t_{1/2} = \frac{0.693}{k} \] where \( k \) is the rate constant of the reaction. 3. **Analyzing the Given Statement**: The statement claims that the half-life is \( 0.263 k \). We need to compare this with the established formula for half-life. 4. **Comparing the Two Expressions**: According to the formula, the half-life is inversely proportional to the rate constant \( k \). The expression \( 0.263 k \) does not match the half-life formula \( \frac{0.693}{k} \). 5. **Conclusion**: Since \( 0.263 k \) does not equal \( \frac{0.693}{k} \), the statement is false. ### Final Answer: The statement "For a first-order reaction, the half-life period is 0.263 k" is **False**. ---
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL KINETICS-Exercises True/False
  1. For a zero order reaction, The rate becomes double when the concentrat...

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  2. For a zero order reaction, the half-life periof is independent of the ...

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  3. x g of a radioactive substance will be decomposed to 7//8x g in 40 s i...

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  4. For a first order reaction, the half-life periof is 0.263 k. T or F

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  5. The sum of powers to which of the concentration terms are raised in th...

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  6. The difference between the energy maximum along a reaction path and th...

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  7. The graph between log k versus 1//T is a straight line.

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  8. The slope of the tangent drawn on velocity-time graph at any instant o...

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  9. A poistive catalyst increases the activation energy of the reaction.

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  10. The slope of straight line in a plot of log.[A] versus time for a firs...

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  11. The rate of reaction increases with increase in activation energy.

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  12. The average rate and instantaneous rate are the same. T or F

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  13. Longer the reaction life time, faster is the reaction. T or F

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  14. A mixture of reactants may be thermodynamically unstable but kinetical...

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  15. The rate constant of a specific reaction is independent of the concent...

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  16. The order of reaction can never be zero.

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  17. In a gaseous reaction, an increase in the pressure of the reactant gas...

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  18. The hydrolyiss of ethyl acetate in the pressure of sofium hydroxide is...

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  19. The unit of rate constant for a zero order reaction is s^(-1).

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  20. In a second order reaction, the plot of 1//(a-x) versus t is a straigh...

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