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A poistive catalyst increases the activa...

A poistive catalyst increases the activation energy of the reaction.

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### Step-by-Step Solution: 1. **Understanding the Statement**: The statement claims that a positive catalyst increases the activation energy of a reaction. We need to analyze whether this statement is true or false. 2. **Definition of Positive Catalyst**: A positive catalyst is a substance that increases the rate of a chemical reaction. It does this by providing an alternative reaction pathway. 3. **Role of Activation Energy**: Activation energy is the minimum energy required for a reaction to occur. It is the energy barrier that must be overcome for reactants to be transformed into products. 4. **Effect of Positive Catalyst on Activation Energy**: A positive catalyst does not increase the activation energy; instead, it lowers it. By providing an alternative pathway with a lower activation energy, the catalyst allows more reactant molecules to have enough energy to react. 5. **Graphical Representation**: If we were to plot a graph with energy on the y-axis and the progress of the reaction on the x-axis, the activation energy can be represented as the difference in energy between the reactants and the peak of the energy barrier (transition state). The presence of a catalyst would lower this peak, indicating a decrease in activation energy. 6. **Conclusion**: Since a positive catalyst decreases the activation energy rather than increasing it, the original statement is false. ### Final Answer: The statement "A positive catalyst increases the activation energy of the reaction" is false. A positive catalyst actually decreases the activation energy, thereby increasing the rate of reaction. ---
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL KINETICS-Exercises True/False
  1. For a zero order reaction, The rate becomes double when the concentrat...

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  2. For a zero order reaction, the half-life periof is independent of the ...

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  3. x g of a radioactive substance will be decomposed to 7//8x g in 40 s i...

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  4. For a first order reaction, the half-life periof is 0.263 k. T or F

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  5. The sum of powers to which of the concentration terms are raised in th...

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  6. The difference between the energy maximum along a reaction path and th...

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  7. The graph between log k versus 1//T is a straight line.

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  8. The slope of the tangent drawn on velocity-time graph at any instant o...

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  9. A poistive catalyst increases the activation energy of the reaction.

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  10. The slope of straight line in a plot of log.[A] versus time for a firs...

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  11. The rate of reaction increases with increase in activation energy.

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  12. The average rate and instantaneous rate are the same. T or F

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  13. Longer the reaction life time, faster is the reaction. T or F

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  14. A mixture of reactants may be thermodynamically unstable but kinetical...

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  15. The rate constant of a specific reaction is independent of the concent...

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  16. The order of reaction can never be zero.

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  17. In a gaseous reaction, an increase in the pressure of the reactant gas...

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  18. The hydrolyiss of ethyl acetate in the pressure of sofium hydroxide is...

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  19. The unit of rate constant for a zero order reaction is s^(-1).

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  20. In a second order reaction, the plot of 1//(a-x) versus t is a straigh...

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