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In a gaseous reaction, an increase in th...

In a gaseous reaction, an increase in the pressure of the reactant gases increases the rate of reaction.T or F

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To determine whether the statement "In a gaseous reaction, an increase in the pressure of the reactant gases increases the rate of reaction" is true or false, we can analyze the relationship between pressure and reaction rate in gaseous reactions. ### Step-by-Step Solution: 1. **Understanding the Reaction**: Consider a generic gaseous reaction where reactant A converts to product B. We can express this reaction as: \[ A(g) \rightarrow B(g) \] 2. **Rate of Reaction**: The rate of a reaction can be expressed in terms of the change in concentration (or pressure in the case of gases) of the reactants over time. For a gaseous reactant A, the rate can be defined as: \[ \text{Rate} = -\frac{d[P_A]}{dt} \] where \( P_A \) is the pressure of gas A. 3. **Rate Law Expression**: The rate of reaction can also be expressed using a rate law, which is dependent on the concentration (or pressure) of the reactants. For a reaction of order \( n \), the rate can be expressed as: \[ \text{Rate} = k \cdot P_A^n \] where \( k \) is the rate constant and \( n \) is the order of the reaction. 4. **Effect of Pressure on Rate**: If we increase the pressure of the reactant gas A, this effectively increases its concentration. According to the rate law, if \( P_A \) increases, then \( P_A^n \) will also increase, leading to an increase in the rate of reaction. 5. **Conclusion**: Since increasing the pressure of the reactant gases leads to an increase in the rate of reaction, we conclude that the statement is true. ### Final Answer: **True**
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL KINETICS-Exercises True/False
  1. For a zero order reaction, The rate becomes double when the concentrat...

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  2. For a zero order reaction, the half-life periof is independent of the ...

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  3. x g of a radioactive substance will be decomposed to 7//8x g in 40 s i...

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  4. For a first order reaction, the half-life periof is 0.263 k. T or F

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  5. The sum of powers to which of the concentration terms are raised in th...

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  6. The difference between the energy maximum along a reaction path and th...

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  7. The graph between log k versus 1//T is a straight line.

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  8. The slope of the tangent drawn on velocity-time graph at any instant o...

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  9. A poistive catalyst increases the activation energy of the reaction.

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  10. The slope of straight line in a plot of log.[A] versus time for a firs...

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  11. The rate of reaction increases with increase in activation energy.

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  12. The average rate and instantaneous rate are the same. T or F

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  13. Longer the reaction life time, faster is the reaction. T or F

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  14. A mixture of reactants may be thermodynamically unstable but kinetical...

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  15. The rate constant of a specific reaction is independent of the concent...

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  16. The order of reaction can never be zero.

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  17. In a gaseous reaction, an increase in the pressure of the reactant gas...

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  18. The hydrolyiss of ethyl acetate in the pressure of sofium hydroxide is...

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  19. The unit of rate constant for a zero order reaction is s^(-1).

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  20. In a second order reaction, the plot of 1//(a-x) versus t is a straigh...

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