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The hydrolyiss of ethyl acetate in the p...

The hydrolyiss of ethyl acetate in the pressure of sofium hydroxide is a first order reaction. T or F

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To determine whether the hydrolysis of ethyl acetate in the presence of sodium hydroxide is a first-order reaction, let's analyze the reaction step by step. ### Step 1: Understand the Reaction The hydrolysis of ethyl acetate (CH3COOCH2CH3) in the presence of sodium hydroxide (NaOH) can be represented as follows: \[ \text{CH}_3\text{COOCH}_2\text{CH}_3 + \text{NaOH} \rightarrow \text{CH}_3\text{COONa} + \text{C}_2\text{H}_5\text{OH} \] ### Step 2: Identify the Reactants In this reaction, the reactants are ethyl acetate and sodium hydroxide. The products formed are sodium acetate (CH3COONa) and ethanol (C2H5OH). ### Step 3: Determine the Rate Law The rate of a reaction can be expressed in terms of the concentrations of the reactants. For this reaction, the rate law can be written as: \[ \text{Rate} = k[\text{CH}_3\text{COOCH}_2\text{CH}_3]^m[\text{NaOH}]^n \] Where \( m \) and \( n \) are the orders of the reaction with respect to ethyl acetate and sodium hydroxide, respectively. ### Step 4: Analyze the Reaction Order In the case of the hydrolysis of esters like ethyl acetate in the presence of a strong base such as sodium hydroxide, the reaction is typically second-order overall. This is because both reactants (ethyl acetate and sodium hydroxide) are involved in the rate-determining step of the reaction. Thus, if we assume \( m = 1 \) and \( n = 1 \), the overall order of the reaction would be: \[ \text{Overall order} = m + n = 1 + 1 = 2 \] ### Step 5: Conclusion Since the overall order of the reaction is 2, the statement that the hydrolysis of ethyl acetate in the presence of sodium hydroxide is a first-order reaction is **false**. ### Final Answer The statement is **False**. ---
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL KINETICS-Exercises True/False
  1. For a zero order reaction, The rate becomes double when the concentrat...

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  2. For a zero order reaction, the half-life periof is independent of the ...

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  3. x g of a radioactive substance will be decomposed to 7//8x g in 40 s i...

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  4. For a first order reaction, the half-life periof is 0.263 k. T or F

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  5. The sum of powers to which of the concentration terms are raised in th...

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  6. The difference between the energy maximum along a reaction path and th...

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  7. The graph between log k versus 1//T is a straight line.

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  8. The slope of the tangent drawn on velocity-time graph at any instant o...

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  9. A poistive catalyst increases the activation energy of the reaction.

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  10. The slope of straight line in a plot of log.[A] versus time for a firs...

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  11. The rate of reaction increases with increase in activation energy.

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  12. The average rate and instantaneous rate are the same. T or F

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  13. Longer the reaction life time, faster is the reaction. T or F

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  14. A mixture of reactants may be thermodynamically unstable but kinetical...

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  15. The rate constant of a specific reaction is independent of the concent...

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  16. The order of reaction can never be zero.

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  17. In a gaseous reaction, an increase in the pressure of the reactant gas...

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  18. The hydrolyiss of ethyl acetate in the pressure of sofium hydroxide is...

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  19. The unit of rate constant for a zero order reaction is s^(-1).

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  20. In a second order reaction, the plot of 1//(a-x) versus t is a straigh...

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