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Why NiO and FeO are nonstroichiometric w...

Why `NiO` and `FeO` are nonstroichiometric with the formula `Ni_(0.98)O` and `Fe_(0.95)O`?

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To understand why \( \text{NiO} \) and \( \text{FeO} \) are non-stoichiometric compounds represented as \( \text{Ni}_{0.98}\text{O} \) and \( \text{Fe}_{0.95}\text{O} \), we need to explore the concepts of oxidation states and electrical neutrality in these compounds. ### Step-by-Step Solution: 1. **Definition of Non-Stoichiometric Compounds**: Non-stoichiometric compounds do not have a fixed ratio of elements as described by a simple formula. Instead, they exhibit variations in composition due to the presence of vacancies or defects in their crystal lattice. 2. **Oxidation States of Nickel in \( \text{NiO} \)**: ...
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Analyses shows that FeO has a non-stoichiometric composition with formula Fe_(0.95)O_(1.00) . Give reason.

Analyses shows that FeO has a non-stoichiometric composition with formula Fe_(0.95)O_(1.00) . Give reason.

STATEMENT -1 : FeO is non-stoichiometric with formula Fe_(0.95)O . STATEMENT -2 : Some Fe^(2+) ions are replaced by Fe^(3+) as 3Fe^(2+) = 2Fe^(3+) to maintain electrons neutrality .

FeO crystallizes in NaCl -type of crystal lattice. The crystals of FeO are deficient in iron and are always non-stoichiometric. Some cationic sites are vacant and some contain Fe^(3+) ions but the combination is such that the structure is elctrically neutral. The formula approximates to Fe_(0.95)O . What is the ratio of Fe^(2+) to Fe^(3+) ions in the solid?

Analysis shows that an oxide ore of nickel has formula Ni_(0.98) O_(1.00) . The percentage of nickel as Ni^(3+) ions is nearly

Ferrous oxide (FeO) is experimentally found to have the formul Fe_(0.93)O . Find the %age of Fe ions in +3 state

The common name of the ore of iron - whose chemical formula is Fe_(3)O_(4)

Which among FeO and Fe_2O_3 is more basic?

The % of Fe^(+2) in Fe_(0.93)O_(1.00) is .

Analysis shows that nickel oxide has the formula Ni_(0.98)O_(1.00) . What fractions of nickel "exist" as Ni^(2+) and Ni^(3+) ions?

CENGAGE CHEMISTRY ENGLISH-NCERT BASED EXERCISE-Short Answer Type Questions
  1. How can a substance be made amorphous?

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  2. Why does ZnO show increased electrical conductivity and turns yellow o...

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  3. Why NiO and FeO are nonstroichiometric with the formula Ni(0.98)O and ...

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  4. Why the defectsof the crystalline solids are called thermodynamic defe...

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  5. Why stoichiometric defects are also called intrinsic defects?

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  6. Give the name of one solid which shows both Schottky and Frenkel defec...

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  7. why is Frenkel defects not found in pure alkali metal halides ?

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  8. why does table salt ,NaCl sometimes appear yellow in colour?

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  9. How do the electrical conductivity and resistivity of metallic conduct...

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  10. What is energy gap in bond theory?

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  11. What is photo voltaic cell?

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  12. What happens when ferrimagnetic Fe(3)O(4) is heated to 850 K?

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  13. What happens when ferromagnetic substance is heated to high temperatur...

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  14. Which type of defect is product when NaCl is dopped with AlCl(3)?

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  15. Which point defect lowers the density of a crystal?

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  16. At what temperature range most of the metals becomes superconductors

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  17. What is curie temperature?

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  18. Name the compound that can be added to AgCl so as to produce cation va...

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  19. Why does Frenkel defect not change the density of AgCl crystals?

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  20. What other elements may be added to silicon to make electrons availabl...

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