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What is shape selective catalysis?...

What is shape selective catalysis?

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It is a chemical reaction in which the rate depends on the pore size of the catalyst, on the shape and size of the reactant, and product molecules. A shape`-`selective catalyst has a variety of active sites of different shape and sizes. Zeolites acts as a shape `-` selective catalyst. In the crystal of a zeolite the pore size usually varies from `260pm` to `740pm`. If the reactant molecules are too large they cannot fit into pores of zeolite and not reaction takes place. On the other hand, if the reactant molecules are too small, they would just slip through the pores in the catalyst without any interactions. `ZSM-5` is used as a shape`-`selective catalyst to produce gasoline of hidh oxtane number from methanol.
`xCH_(3)OHunderset(Catalyst)overset(ZSM-5)rarrunderset(Gasoli n e)((CH_(2)))+xH_(2)O`
where `x` varies from 5 to 10. `ZSM-5` stands for zeolite sieve of molecular porosity 5.
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CENGAGE CHEMISTRY ENGLISH-NCERT BASED EXERCISE-NCERT Exercise
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  2. Why is a absorption always exothermic ?

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  3. How are the colloidal solutions classified on the basis of physical st...

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  6. What is the difference between multimolecular and macromolecular collo...

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  7. What are enzymes?

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  8. State the observation when Table salt is added to hydrated ferric oxid...

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  9. What are emulsions ? What are their different types ? Give an example ...

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  10. How do emulsifying agents stabilise the emulsion?

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  11. Action of soap is due to emulsification and micellel formation. Commen...

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  12. Give four examples of heterogeneous catalysis.

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  13. What do you mean by activity and selectivity of catalysts?

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  14. Describe some features of catalysis by zeolites.

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  15. What is shape selective catalysis?

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  16. Explain the following terms: (i) Electrophoresis (ii) Coagulation ...

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  17. Give four uses of emulsions.

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  18. What are micelles? Given an example of micelle system.

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  19. Explain the terms with suitable examples: (i) Alcosol (ii) Aerosol (...

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  20. Comment on the statement that colloid is not a substance but a state o...

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