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The number of sigma- and pi-bond in 5-ox...

The number of `sigma`- and `pi`-bond in 5-oxohexanoic acid, respectively, is :

A

18,2

B

18,1

C

17,2

D

17,1

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The correct Answer is:
To determine the number of sigma (σ) and pi (π) bonds in 5-oxohexanoic acid, we will follow these steps: ### Step 1: Understand the Structure of 5-oxohexanoic Acid 5-oxohexanoic acid is a carboxylic acid with a ketone group. The name indicates that the compound has a total of 6 carbon atoms (hexanoic) and a ketone group (oxo) at the 5th position. ### Step 2: Draw the Structure 1. Start by drawing a straight chain of 6 carbon atoms. 2. At the 5th carbon, add a ketone group (C=O). 3. At the 6th carbon, add a carboxylic acid group (–COOH). The structure can be represented as: ``` O || C-C-C-C-C-COOH ``` ### Step 3: Count the Sigma Bonds 1. **C-C Sigma Bonds**: Count the single bonds between carbon atoms. There are 5 C-C bonds in the chain. 2. **C-H Sigma Bonds**: Count the hydrogen atoms attached to each carbon. The 1st, 2nd, 3rd, and 4th carbons will have 2 hydrogen atoms each, while the 5th carbon (attached to the ketone) will have 1 hydrogen, and the 6th carbon (attached to the carboxylic acid) will have no hydrogen. This gives us: - 1st C: 2 H - 2nd C: 2 H - 3rd C: 2 H - 4th C: 2 H - 5th C: 1 H - 6th C: 0 H Total = 2 + 2 + 2 + 2 + 1 + 0 = 9 C-H sigma bonds. 3. **C-O Sigma Bonds**: There are 2 C-O bonds (one from the ketone and one from the carboxylic acid). 4. **OH Sigma Bond**: There is 1 OH bond in the carboxylic acid. Adding these together: - C-C sigma bonds: 5 - C-H sigma bonds: 9 - C-O sigma bonds: 2 - OH sigma bond: 1 Total σ bonds = 5 + 9 + 2 + 1 = 17 σ bonds. ### Step 4: Count the Pi Bonds 1. **C=O (from the ketone)**: There is 1 π bond from the ketone group. 2. **C=O (from the carboxylic acid)**: There is another π bond from the carboxylic acid. Total π bonds = 1 + 1 = 2 π bonds. ### Final Answer The number of sigma (σ) and pi (π) bonds in 5-oxohexanoic acid is: - **Sigma bonds (σ)**: 17 - **Pi bonds (π)**: 2

To determine the number of sigma (σ) and pi (π) bonds in 5-oxohexanoic acid, we will follow these steps: ### Step 1: Understand the Structure of 5-oxohexanoic Acid 5-oxohexanoic acid is a carboxylic acid with a ketone group. The name indicates that the compound has a total of 6 carbon atoms (hexanoic) and a ketone group (oxo) at the 5th position. ### Step 2: Draw the Structure 1. Start by drawing a straight chain of 6 carbon atoms. 2. At the 5th carbon, add a ketone group (C=O). ...
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CENGAGE CHEMISTRY ENGLISH-CLASSIFICATION AND NOMENCLATURE OF ORGANIC COMPOUNDS-Single correct Answer Type
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  2. The number of sigma- and pi-bond in hexan-2,4-diol, respectively,is:

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  3. The number of sigma- and pi-bond in 5-oxohexanoic acid, respectively, ...

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  4. Which of the following is correctly named?

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  5. The systematic naming of the following cycloalkane is

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  6. In which of the following reactions, the principal group loses its pre...

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  7. Which of the following is oxetane?

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  8. The systematic nomencalutre of the following spiro-compound is:

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  9. An alkane (A) having a molecular mass of 72 produces one monochlorinat...

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  10. A compound (A) with molecular formula C(5) H(10) gives one monochlorin...

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  11. Which of the following the following in a 3^(@) amine?

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  12. Which of the following as a 3^(@) alcohol?

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  13. Which of the following is zerone?

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  14. Which of the following is pyrogallol?

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  15. In 3-chloro cyclohexanol, the primary prefix is:

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  16. In 2-Chloro-3-methy1 hexanoic acid, the primary suffix is:

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  17. The correct name of the compound (I) is:

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  18. Which of the following is not a cumulated diene?

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  19. Which of the following has only 1^(@) and 2^(@)C atoms?

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  20. The IUPAC name of viny1 acetylene is:

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