Home
Class 11
CHEMISTRY
Answer the following question (Based on ...

Answer the following question (Based on `EA, Delta_(eg)H^(ɵ)` and `IE`).
`IE_(1)` of `Li` is `5.4 eV "atom"^(-1)` and the `EA` of `Cl` is `3.6 eV "atom"^(-1)`. Calculate `Delta_( r)H^(ɵ)` in `"kcal mol"^(-1)` and `kJ mol^(-1)` for the reaction
`Li_((g))+Cl_((g)) rarr Li_((g))^(o+)+Cl_((g))^(ɵ)`
formed at such a low pressure that resulting ions do not combine with each other.

Text Solution

AI Generated Solution

To solve the problem, we need to calculate the standard enthalpy change (ΔH) for the reaction: \[ \text{Li}_{(g)} + \text{Cl}_{(g)} \rightarrow \text{Li}^{+}_{(g)} + \text{Cl}^{-}_{(g)} \] We are given the following data: - Ionization Energy (IE₁) of Lithium (Li) = 5.4 eV - Electron Affinity (EA) of Chlorine (Cl) = 3.6 eV ...
Promotional Banner

Topper's Solved these Questions

  • PERIODIC CLASSIFICATION OF ELEMENTS AND GENERAL INORGANIC CHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 1.1|14 Videos
  • PERIODIC CLASSIFICATION OF ELEMENTS AND GENERAL INORGANIC CHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Ex 1.1 (Very Short)|22 Videos
  • PERIODIC CLASSIFICATION OF ELEMENTS AND GENERAL INORGANIC CHEMISTRY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises (Archives )Subjective|4 Videos
  • P-BLOCK GROUP 14 - CARBON FAMILY

    CENGAGE CHEMISTRY ENGLISH|Exercise Exercises Archives (Subjective)|9 Videos
  • PURIFICATION OF ORGANIC COMPOUNDS AND QUALITATIVE AND QUANTITATIVE ANALYSIS

    CENGAGE CHEMISTRY ENGLISH|Exercise Assertion Reasoning Type|5 Videos

Similar Questions

Explore conceptually related problems

If the first ionization enthalpy of Li is 5.4 eV and the elec- tron gain enthalpy of chlorine is 3.6 eV then the Delta H in kcal/mole for the reaction will be Li(g)+Cl(g) to Li^(+) (g) Cl^(-) (g) (Presume that the pressure is so low that the ions do not combine with each other)

Calculate DeltaH^(@) ("in" kJmol^(-1)) for the reaction CH_(2)Cl_(2)(g)rarrC(g)+2H(g)+2Cl(g). The average bond enthalpie of C-H and C-C1 bonds are 414 kJ mol^(-1) .

The IE_(1) of Li is 5.4 eV and IE_(1) of H is 13.6 eV . Calculate the charge acting on the outermost electron of Li atom.

DeltaG^(ɵ) for 1/2 N_(2)(g)+3/2H_(2)(g) hArrNH_(3)(g) is -16.5 kJ mol^(-1) . Find out K_(p) for the reaction at 25^(@)C .

For the reaction : C_(2)H_(5)OH(l)+3O_(2)(g)rarr2CO_(2)(g)+3H_(2)O(g) if Delta U^(@)= -1373 kJ mol^(-1) at 298 K . Calculate Delta H^(@)

The amount of energy released when 10^(12) atoms of Cl vapours are converted to Cl^(ɵ) ions, according to the equation : Cl_((g))+e^(-) rarr Cl_((g))^(ɵ) is 58 xx 10^(-10)J Calculate the Delta_(eg)H^(ɵ) of Cl atom in kJ mol^(-1) and eV "atom"^(-1) .

Given below are the values of DeltaH^(ɵ) and DeltaS^(ɵ) for the reaction given below at 27^(@)C . SO_(2)(g)+1/2O_(2)(g) rarr SO_(3)(g) DeltaH^(ɵ)=-98.32 kJ mol^(-1), DeltaS^(ɵ)=-95 J mol^(-1) Find K_(p) for the reaction

Determine enthalpy change for the reaction, CH_(4(g))+Cl_(2(g))rarr CH_(3)Cl_((g))+HCl_((g)) Bond energies for C-H,C-Cl,Cl-Cl,H-Cl are 412,338,242,431k J mol^(-1) respectively.

Delta H_(1)^(@) for CO_(2)(g) , CO(g) and H_(2)O(g) are -393.5,-110.5 and -241.8 kJ mol^(-1) respectively. Standard enthalpy change for the reaction CO_(2)(g)+H_(2)(g) rarr CO(g) + H_(2)O(g) is

The following reaction was carried out in water : Cl_(2) + 2I^(ɵ) rarr I_(2) + 2Cl^(ɵ) The initial concentration of I^(ɵ) was 0.25 mol L^(-1) and the concentration after 10 min was 0.23 mol L^(-1) . Calculate the rate of disappearance of I^(ɵ) and rate of appearance of I_(2) .

CENGAGE CHEMISTRY ENGLISH-PERIODIC CLASSIFICATION OF ELEMENTS AND GENERAL INORGANIC CHEMISTRY-Solved Examples
  1. Among the elements with Z = 9, 12 and 36, identify by atomic number of...

    Text Solution

    |

  2. Explain the question (based on ionisation energy): (a) Why IE(1) of ...

    Text Solution

    |

  3. Answer the following question (Based on EA, Delta(eg)H^(ɵ) and IE). I...

    Text Solution

    |

  4. a. Arrange the following species in decreasing order of their sizes//i...

    Text Solution

    |

  5. For the gaseous reaction K+F rarrK^(o+)+F^(ɵ) Delta H = 19 kcal mo...

    Text Solution

    |

  6. For the gaseous reaction K+F rarrK^(o+)+F^(ɵ) Delta H = 19 kcal mo...

    Text Solution

    |

  7. From N atoms of an element A, when half the atoms transfer one electro...

    Text Solution

    |

  8. The conservation of gaseous atoms K and F to K^(o+) and F^(ɵ) absorbs ...

    Text Solution

    |

  9. Which of the following Na, Mg, Si and P would have the greatest differ...

    Text Solution

    |

  10. Classify the following oxides as a. Strongly acidic b. Weakly acidic...

    Text Solution

    |

  11. Select the strongest and weakest acid in each of the following sets: ...

    Text Solution

    |

  12. A 0.10 M aqueous solution of which salt in the following pair would ha...

    Text Solution

    |

  13. Identify: a. The good oxidising agent b. The good reducing agent ...

    Text Solution

    |

  14. Which of the following has the greatest affinity for water: P(4)O(10)....

    Text Solution

    |

  15. Why Al^(3+) is the only stable oxidation state of Al in its compounds ...

    Text Solution

    |

  16. Give the name and atomic number of the inert gas atom in which the tot...

    Text Solution

    |

  17. Classify the elements having atomic numbers (9,12,16,34,53,56) into th...

    Text Solution

    |

  18. Calculate the electronegativity of fluorine from the following data: ...

    Text Solution

    |

  19. Calculate electronegativity of carbon at Pauling scale Given that : ...

    Text Solution

    |

  20. Ionisation potential and electron affinity of fluorine are 17.42 and 3...

    Text Solution

    |