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Delta(f)H^(ɵ) of hypothetical MX is -150...

`Delta_(f)H^(ɵ)` of hypothetical MX is `-150 kJ mol^(-1)` and for `MX_(2)` is `-600 kJ mol^(-1)`. The enthalpy of disproportionation of MX is `=-100 x kJ mol^(-1)`.
Find the value of x.

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To find the value of \( x \) in the given problem, we will follow these steps: ### Step 1: Understand the Disproportionation Reaction The disproportionation reaction of \( MX \) can be written as: \[ 2 \, MX \rightarrow M + MX_2 \] This means that two moles of \( MX \) decompose into one mole of \( M \) and one mole of \( MX_2 \). ### Step 2: Write the Enthalpy Change for the Disproportionation Reaction The enthalpy change for the disproportionation reaction is given as: \[ \Delta H_{disproportionation} = -100x \, \text{kJ/mol} \] ### Step 3: Use the Enthalpy of Formation Values We know the enthalpy of formation for \( MX \) and \( MX_2 \): - For \( MX \): \[ \Delta_f H^\circ (MX) = -150 \, \text{kJ/mol} \] - For \( MX_2 \): \[ \Delta_f H^\circ (MX_2) = -600 \, \text{kJ/mol} \] ### Step 4: Calculate the Enthalpy Change for the Reaction The enthalpy change for the reaction can also be calculated using the enthalpies of formation: \[ \Delta H_{reaction} = \Delta H_f (products) - \Delta H_f (reactants) \] Substituting the values: \[ \Delta H_{reaction} = \Delta H_f (M) + \Delta H_f (MX_2) - 2 \Delta H_f (MX) \] Since the enthalpy of formation for \( M \) is not given, we will denote it as \( \Delta H_f (M) \). ### Step 5: Set Up the Equation Substituting the known values: \[ \Delta H_{reaction} = \Delta H_f (M) - 600 - 2(-150) \] This simplifies to: \[ \Delta H_{reaction} = \Delta H_f (M) - 600 + 300 \] \[ \Delta H_{reaction} = \Delta H_f (M) - 300 \] ### Step 6: Equate the Two Expressions for Enthalpy Change Now, we can set the two expressions for the enthalpy change equal to each other: \[ -100x = \Delta H_f (M) - 300 \] ### Step 7: Solve for \( x \) To find \( x \), we need to express \( \Delta H_f (M) \). However, we can rearrange the equation: \[ \Delta H_f (M) = -100x + 300 \] Now, we need to find a relationship to eliminate \( \Delta H_f (M) \). We know that the enthalpy of formation for \( M \) should be consistent with the other values. ### Step 8: Assume \( \Delta H_f (M) = 0 \) for simplicity If we assume \( \Delta H_f (M) = 0 \) (which is a common assumption for elements in their standard state), we can substitute this into the equation: \[ 0 = -100x + 300 \] Solving for \( x \): \[ 100x = 300 \] \[ x = 3 \] ### Final Answer Thus, the value of \( x \) is: \[ \boxed{3} \]

To find the value of \( x \) in the given problem, we will follow these steps: ### Step 1: Understand the Disproportionation Reaction The disproportionation reaction of \( MX \) can be written as: \[ 2 \, MX \rightarrow M + MX_2 \] This means that two moles of \( MX \) decompose into one mole of \( M \) and one mole of \( MX_2 \). ...
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