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Along the period (rarr) atomic//ionic ra...

Along the period `(rarr)` atomic`//`ionic radii and metallic character decreases while `IE`, `EN` , non-metallic character and oxidising power increases. Down the group `(darr)`, atomic`//`ionic radii, metallic character and reducing character increase while `IE` and `EN` decrease. However, `Delta_(eg)H^(ɵ)` becomes less negative down a group but more negative along a period.
If the ionic radii of `M^(o+)` and `X^(ɵ)` are about `135 p m`, then expected values of metallic radii of `M` and `X` should be respectively.

A

`65` and `230 p m`

B

`230` and `60 p m`

C

`230` and `135 p m`

D

`135` and `135 p m`

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The correct Answer is:
To solve the problem, we need to understand the relationship between ionic radii and metallic radii for the elements M and X. Given that the ionic radii of M⁺ and X⁻ are both approximately 135 picometers, we can derive the expected values of their metallic radii. ### Step-by-Step Solution: 1. **Understanding Ionic and Metallic Radii**: - The ionic radius of a cation (M⁺) is smaller than its atomic radius (M), while the ionic radius of an anion (X⁻) is larger than its atomic radius (X). - Therefore, if the ionic radius of M⁺ is 135 pm, then the atomic radius of M must be greater than 135 pm. - Conversely, if the ionic radius of X⁻ is 135 pm, then the atomic radius of X must be less than 135 pm. 2. **Setting Up the Relationships**: - For cation M⁺: \[ \text{Ionic radius of M⁺} < \text{Atomic radius of M} \] \[ 135 \text{ pm} < \text{Atomic radius of M} \] - For anion X⁻: \[ \text{Ionic radius of X⁻} > \text{Atomic radius of X} \] \[ 135 \text{ pm} > \text{Atomic radius of X} \] 3. **Estimating the Values**: - Since the ionic radius of M⁺ is 135 pm, we can estimate that the atomic radius of M could be around 230 pm (as cations are generally smaller than their parent atoms). - Since the ionic radius of X⁻ is 135 pm, we can estimate that the atomic radius of X could be around 60 pm (as anions are generally larger than their parent atoms). 4. **Conclusion**: - Therefore, the expected values of the metallic radii of M and X should be: - Metallic radius of M: Greater than 135 pm, likely around 230 pm. - Metallic radius of X: Less than 135 pm, likely around 60 pm. 5. **Final Answer**: - The expected values of metallic radii of M and X are 230 pm and 60 pm, respectively.

To solve the problem, we need to understand the relationship between ionic radii and metallic radii for the elements M and X. Given that the ionic radii of M⁺ and X⁻ are both approximately 135 picometers, we can derive the expected values of their metallic radii. ### Step-by-Step Solution: 1. **Understanding Ionic and Metallic Radii**: - The ionic radius of a cation (M⁺) is smaller than its atomic radius (M), while the ionic radius of an anion (X⁻) is larger than its atomic radius (X). - Therefore, if the ionic radius of M⁺ is 135 pm, then the atomic radius of M must be greater than 135 pm. - Conversely, if the ionic radius of X⁻ is 135 pm, then the atomic radius of X must be less than 135 pm. ...
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