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Which of the following statement (s) is/...

Which of the following statement `(s)` is`//are` correct ?

A

The element which has higher `EA` acts as a strong oxidising agent.

B

The element with higher `EA` has higher `IE`.

C

Along a period halogen has maximum `EA`.

D

The decreasing order of `EA` is `F gt Cl gt Br`.

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the statements regarding electron affinity and oxidizing agents are correct, we will analyze each statement step by step. ### Step 1: Analyze the first statement **Statement:** The element which has higher electron affinity acts as a strong oxidizing agent. **Analysis:** - Generally, elements with higher electron affinity tend to be strong oxidizing agents because they can easily gain electrons. - However, there is an exception with fluorine and chlorine. Chlorine has a higher electron affinity than fluorine, but fluorine is a stronger oxidizing agent than chlorine. - Therefore, while the statement is generally true, it has exceptions. **Conclusion:** This statement is considered correct in general, but with exceptions. ### Step 2: Analyze the second statement **Statement:** The element with higher electron affinity has higher ionization enthalpy. **Analysis:** - Higher electron affinity is typically associated with smaller atomic size, which also leads to higher ionization enthalpy. - As we move across a period, both electron affinity and ionization enthalpy tend to increase. - Thus, this statement holds true in general. **Conclusion:** This statement is correct. ### Step 3: Analyze the third statement **Statement:** Along a period, halogen has maximum electron affinity. **Analysis:** - Halogens indeed have the highest electron affinity among all groups in the periodic table. - As we move from left to right across a period, the tendency to gain electrons increases, confirming that halogens have maximum electron affinity. **Conclusion:** This statement is correct. ### Step 4: Analyze the fourth statement **Statement:** The decreasing order of electron affinity is Fluorine, Chlorine, then Bromine. **Analysis:** - The correct order of electron affinity for halogens is Chlorine > Fluorine > Bromine > Iodine. - Fluorine has a lower electron affinity than chlorine due to increased inter-electronic repulsion in its small size. - Therefore, this statement is incorrect. **Conclusion:** This statement is incorrect. ### Final Conclusion: The correct statements are: 1. The element which has higher electron affinity acts as a strong oxidizing agent (with exceptions). 2. The element with higher electron affinity has higher ionization enthalpy. 3. Along a period, halogen has maximum electron affinity. ### Correct Options: - Option 1: Correct - Option 2: Correct - Option 3: Correct - Option 4: Incorrect
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