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Assertion (A) : EA of O is less than tha...

Assertion (A) : `EA` of `O` is less than that of `F` but greater than that of `N`.
Reason (R ): `IE` is as follows: `N gt O gt F`.

A

If both Assertion (A) and (R ) are correct and Reason (R ) is the correct explanation of Assertion (A).

B

If both (A) and (R ) are correct but (R ) is not the correct explanation for (A).

C

If (A) is correct but (R ) is not correct.

D

If (A) and (R ) are correct

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we will analyze both the assertion (A) and the reason (R) provided. ### Step 1: Understanding Electron Affinity (EA) - **Definition**: Electron affinity is the amount of energy released when an electron is added to a neutral atom in the gaseous state to form a negative ion. - **Trend**: Generally, electron affinity increases across a period from left to right due to increasing nuclear charge, which attracts electrons more strongly. ### Step 2: Analyzing the Assertion (A) - **Assertion**: "EA of O is less than that of F but greater than that of N." - **Analysis**: - **Fluorine (F)**: Has the highest electron affinity because it has seven valence electrons and needs one more to achieve a stable octet. - **Oxygen (O)**: Has six valence electrons and thus has a strong attraction for an additional electron, but less than fluorine. - **Nitrogen (N)**: Has five valence electrons and is less eager to gain an electron compared to oxygen. - **Conclusion**: The assertion is correct: EA(O) < EA(F) and EA(O) > EA(N). ### Step 3: Understanding Ionization Energy (IE) - **Definition**: Ionization energy is the energy required to remove an electron from a neutral atom in the gaseous state to form a positive ion. - **Trend**: Ionization energy generally increases across a period due to increasing nuclear charge. ### Step 4: Analyzing the Reason (R) - **Reason**: "IE is as follows: N > O > F." - **Analysis**: - The correct trend for ionization energy is actually: F > O > N. - Fluorine has the highest ionization energy because it is close to achieving a full octet and does not want to lose an electron. - Oxygen has a higher ionization energy than nitrogen because it has a higher nuclear charge, making it harder to remove an electron from oxygen than from nitrogen. - **Conclusion**: The reason provided is incorrect. ### Final Conclusion - The assertion is correct, but the reason is incorrect. Therefore, the correct answer is that the assertion is true, but the reason is false.

To solve the question, we will analyze both the assertion (A) and the reason (R) provided. ### Step 1: Understanding Electron Affinity (EA) - **Definition**: Electron affinity is the amount of energy released when an electron is added to a neutral atom in the gaseous state to form a negative ion. - **Trend**: Generally, electron affinity increases across a period from left to right due to increasing nuclear charge, which attracts electrons more strongly. ### Step 2: Analyzing the Assertion (A) - **Assertion**: "EA of O is less than that of F but greater than that of N." ...
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