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Assertion (A): IE(1) of N is lower than ...

Assertion (A): `IE_(1)` of `N` is lower than `O`.
Reason (R ) : Across a period `Z_(eff)` decrease.

A

If both Assertion (A) and (R ) are correct and Reason (R ) is the correct explanation of Assertion (A).

B

If both (A) and (R ) are correct but (R ) is not the correct explanation for (A).

C

If (A) is correct but (R ) is not correct.

D

If both (A) and (R ) are correct

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given assertion and reason, we will break down the concepts of ionization energy and effective nuclear charge. ### Step-by-Step Solution: 1. **Understanding Ionization Energy (IE)**: - Ionization energy is defined as the energy required to remove an electron from the outermost shell of a neutral gaseous atom. - Higher ionization energy indicates that it is more difficult to remove an electron. 2. **Electron Configuration of Nitrogen and Oxygen**: - Nitrogen (N) has the electron configuration of \(1s^2 2s^2 2p^3\). - Oxygen (O) has the electron configuration of \(1s^2 2s^2 2p^4\). 3. **Stability of Half-filled Configuration**: - Nitrogen has a half-filled p-orbital configuration (2p^3), which is relatively stable. This stability makes it harder to remove an electron from nitrogen. - Oxygen, on the other hand, has one more electron in the p-orbital (2p^4), which makes it less stable than nitrogen when it comes to losing an electron. 4. **Comparing Ionization Energies**: - Due to the half-filled stability, nitrogen has a higher ionization energy compared to oxygen. Therefore, the assertion that the ionization energy of nitrogen (IE1 of N) is lower than that of oxygen (IE1 of O) is incorrect. 5. **Understanding Effective Nuclear Charge (Z_eff)**: - Effective nuclear charge is the net positive charge experienced by electrons in the outer shell. - As we move across a period from left to right, the number of protons increases while the shielding effect remains relatively constant, leading to an increase in effective nuclear charge. 6. **Assertion and Reason Analysis**: - The assertion (A) is incorrect because the ionization energy of nitrogen is actually higher than that of oxygen. - The reason (R) is also incorrect because effective nuclear charge (Z_eff) increases across a period, not decreases. ### Conclusion: Both the assertion and the reason provided in the question are incorrect.

To analyze the given assertion and reason, we will break down the concepts of ionization energy and effective nuclear charge. ### Step-by-Step Solution: 1. **Understanding Ionization Energy (IE)**: - Ionization energy is defined as the energy required to remove an electron from the outermost shell of a neutral gaseous atom. - Higher ionization energy indicates that it is more difficult to remove an electron. ...
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