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Among BeCO(3), CaCO(3), SrCO(3) and BaCO...

Among `BeCO_(3), CaCO_(3), SrCO_(3)` and `BaCO_(3)`, how many number than of these compounds are thermally more stable than `MgCO_(3)` ?

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To determine how many of the compounds \( BeCO_3, CaCO_3, SrCO_3, \) and \( BaCO_3 \) are thermally more stable than \( MgCO_3 \), we need to analyze the thermal stability of these carbonates based on their position in the periodic table. ### Step-by-Step Solution: 1. **Understanding Thermal Stability**: - The thermal stability of carbonates generally increases as we move down the group in the periodic table. This is due to the increasing size of the cation, which leads to a decrease in the lattice energy and makes the compound more stable against thermal decomposition. 2. **Order of Stability**: - For alkaline earth metal carbonates, the order of thermal stability is: \[ BaCO_3 > SrCO_3 > CaCO_3 > MgCO_3 \] - This means that barium carbonate is the most stable, followed by strontium carbonate, then calcium carbonate, and finally magnesium carbonate. 3. **Analyzing Each Compound**: - **Beryllium Carbonate (\( BeCO_3 \))**: - Beryllium carbonate is known to be thermally unstable due to the high polarizing power of beryllium, which destabilizes the carbonate ion. Therefore, \( BeCO_3 \) is not more stable than \( MgCO_3 \). - **Calcium Carbonate (\( CaCO_3 \))**: - Calcium carbonate is less stable than magnesium carbonate according to the order established above. Thus, \( CaCO_3 \) is not more stable than \( MgCO_3 \). - **Strontium Carbonate (\( SrCO_3 \))**: - Strontium carbonate is more stable than magnesium carbonate. Therefore, \( SrCO_3 \) is thermally more stable than \( MgCO_3 \). - **Barium Carbonate (\( BaCO_3 \))**: - Barium carbonate is also more stable than magnesium carbonate. Hence, \( BaCO_3 \) is thermally more stable than \( MgCO_3 \). 4. **Conclusion**: - From the analysis, we find: - \( BeCO_3 \): Not more stable than \( MgCO_3 \) - \( CaCO_3 \): Not more stable than \( MgCO_3 \) - \( SrCO_3 \): More stable than \( MgCO_3 \) - \( BaCO_3 \): More stable than \( MgCO_3 \) Therefore, the number of compounds that are thermally more stable than \( MgCO_3 \) is **2** (i.e., \( SrCO_3 \) and \( BaCO_3 \)). ### Final Answer: **2**

To determine how many of the compounds \( BeCO_3, CaCO_3, SrCO_3, \) and \( BaCO_3 \) are thermally more stable than \( MgCO_3 \), we need to analyze the thermal stability of these carbonates based on their position in the periodic table. ### Step-by-Step Solution: 1. **Understanding Thermal Stability**: - The thermal stability of carbonates generally increases as we move down the group in the periodic table. This is due to the increasing size of the cation, which leads to a decrease in the lattice energy and makes the compound more stable against thermal decomposition. 2. **Order of Stability**: ...
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