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Amongst H2O, H2S, H2 Se and H2 Te, the o...

Amongst `H_2O, H_2S, H_2 Se` and `H_2 Te`, the one with the highest boiling point is :

A

`H_(2)O` because of hydrogen bonding

B

`H_(2)Te` because of higher molecular weight

C

`H_(2)S` because of hydrogen boning

D

`H_(2)Se` because of lower molecular weight

Text Solution

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The correct Answer is:
To determine which of the compounds \( H_2O, H_2S, H_2Se, \) and \( H_2Te \) has the highest boiling point, we can follow these steps: ### Step 1: Identify the Compounds The compounds in question are: - \( H_2O \) (water) - \( H_2S \) (hydrogen sulfide) - \( H_2Se \) (hydrogen selenide) - \( H_2Te \) (hydrogen telluride) ### Step 2: Understand the Group Trends All these compounds are hydrides of group 16 elements: - Oxygen (O) for \( H_2O \) - Sulfur (S) for \( H_2S \) - Selenium (Se) for \( H_2Se \) - Tellurium (Te) for \( H_2Te \) As we move down the group from oxygen to tellurium, the molecular weight of the hydrides increases. ### Step 3: Consider Molecular Weight The boiling point of a substance is generally influenced by its molecular weight. The trend in molecular weights for these compounds is: - \( H_2O \) has a molecular weight of approximately 18 g/mol. - \( H_2S \) has a molecular weight of approximately 34 g/mol. - \( H_2Se \) has a molecular weight of approximately 78 g/mol. - \( H_2Te \) has a molecular weight of approximately 130 g/mol. From this trend, we can see that \( H_2Te \) has the highest molecular weight. ### Step 4: Consider Hydrogen Bonding However, boiling points are also significantly affected by the presence of hydrogen bonding. \( H_2O \) exhibits strong hydrogen bonding due to the highly electronegative oxygen atom. This results in a much higher boiling point compared to the other hydrides, which do not exhibit hydrogen bonding to the same extent. ### Step 5: Compare Boiling Points - \( H_2O \) has a boiling point of 100 °C. - \( H_2S \) has a boiling point of -60 °C. - \( H_2Se \) has a boiling point of -41 °C. - \( H_2Te \) has a boiling point of -2 °C. ### Conclusion Despite \( H_2Te \) having the highest molecular weight, the presence of hydrogen bonding in \( H_2O \) leads to it having the highest boiling point among the four compounds. Thus, the compound with the highest boiling point is **\( H_2O \)**. ---

To determine which of the compounds \( H_2O, H_2S, H_2Se, \) and \( H_2Te \) has the highest boiling point, we can follow these steps: ### Step 1: Identify the Compounds The compounds in question are: - \( H_2O \) (water) - \( H_2S \) (hydrogen sulfide) - \( H_2Se \) (hydrogen selenide) - \( H_2Te \) (hydrogen telluride) ...
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