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Expalin (a) H(2)^(o+) and H(2)^(Θ) ion...

Expalin
(a) `H_(2)^(o+)` and `H_(2)^(Θ)` ions have same bond order but `H_(2)^(o+)` ions are more stable than `H_(2)^(Θ)`
(b) It is possible to have a diatomic molecule with its ground sate `MO` s full with electrons
(c ) Why `2p_(x0` or `2p_(y)` orbitals do not combine with 2s orbitals to form `MO` (Taking Z-axis as the internuclear axis) .

Text Solution

Verified by Experts

`MO` Electronic configuration of `H_(2)^(o+)(Z =1) = sigma 1s^(1)`
`MO` Electronic configuration of `H_(2)^(Θ) (Z =1) sigma 1s^(2),overset(**)sigma 1s^(1)`
`H_(2)^(o+)` ion is more stable due to the presence of one electron in bonding `MO` But `H_(2)^(Θ)` is less stable due to the presence of one electron in the antibonding `overset(**)sigma 1s` `MO` due to which there is some destabilising effect
(b) `NO` Because in such case `BO` becomes zero for example in case of `He_(2),Be_(2),Ne_(2)etc`
Note In `H_(2),BO` is one `sigma 1s MO` is full while `overset(**)1s` antibonding `MO` is empty
(c ) Small `(+)(+)` overlap cancels the `(+)(-)` overlap Hence there is no net overlapping .
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Ex 2 .2 Objective
  1. Give the number of electrons which occupy the bonding orbitals in H(2)...

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  2. Compare the relative stabilities and magnetic behaviour of the followi...

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  3. Expalin (a) H(2)^(o+) and H(2)^(Θ) ions have same bond order but H(2...

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  4. Which of the following species have same bond order and same shape (...

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  5. Which of the following is soluble in water

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  6. Which one among the following does not have the hybrogen bond ?

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  7. The molecule having one unpaired electrons is .

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  8. The hydrogen bond is strongest in

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  9. Hydrogen bond is maximum in .

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  10. How many hydrogen bonds can be formed by a water molecule?

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  11. Number of paired electrons in O(2) molecule is .

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  12. Among KO(2) , AlO(2)^(+) , BaO(2) and NO(2)^(+) unpaired electron is p...

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  13. The correct order of decreasing bond lengths of CO,CO(2) and CO(3)^(2-...

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  14. Which of the following statement is correct among the species CN^(Θ),C...

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  15. Which of the following species has unpaired electrons?

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  16. Which of the following are iso-electronic as well as iso-structural ? ...

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  17. According to MO theory which of the following statement about the mag...

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  18. Which of the following compound is paramagnetic ? .

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  19. The species having bond order differnet from that in CO is .

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  20. In forming (i) N(2) rarrN(2)^(o+) and O(2)rarrO(2)^(o+) the electrons ...

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