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The bond order in NO is 2.5 while that i...

The bond order in `NO` is 2.5 while that in `NO^(o+)` is 3 Which of the following statement is true for these two species ? .

A

Bond length in `NO gt "in" NO^(o+)`

B

Bond length in `NO^(o+) = "in" NO`

C

Bond length in `NO^(o+) = "in" NO`

D

Bond length in `NO^(o+) gt "in" NO`

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The correct Answer is:
To determine which statement is true regarding the bond lengths of the species NO and NO^(o+), we will analyze the relationship between bond order and bond length. ### Step-by-Step Solution: 1. **Understanding Bond Order**: - The bond order is a measure of the number of chemical bonds between a pair of atoms. A higher bond order indicates a stronger bond. 2. **Given Information**: - The bond order of NO (Nitric Oxide) is 2.5. - The bond order of NO^(o+) (Nitric Oxide cation) is 3. 3. **Relationship Between Bond Order and Bond Length**: - There is an inverse relationship between bond order and bond length. This means that as the bond order increases, the bond length decreases. - Stronger bonds (higher bond order) result in shorter bond lengths due to increased attraction between the bonded atoms. 4. **Comparing Bond Orders**: - Since the bond order of NO^(o+) (3) is greater than that of NO (2.5), we can conclude that NO^(o+) has a stronger bond. 5. **Conclusion on Bond Lengths**: - Because NO^(o+) has a higher bond order than NO, it will have a shorter bond length. Therefore, the bond length of NO is greater than that of NO^(o+). 6. **Identifying the Correct Statement**: - The statement that the bond length of NO is greater than the bond length of NO^(o+) is true. ### Final Answer: - The bond length of NO is greater than the bond length of NO^(o+).

To determine which statement is true regarding the bond lengths of the species NO and NO^(o+), we will analyze the relationship between bond order and bond length. ### Step-by-Step Solution: 1. **Understanding Bond Order**: - The bond order is a measure of the number of chemical bonds between a pair of atoms. A higher bond order indicates a stronger bond. 2. **Given Information**: ...
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CENGAGE CHEMISTRY ENGLISH-CHEMICAL BONDING AND MOLECULAR STRUCTURE-Exercises Single Correct (Molecular Orbital Theory (Mot))
  1. The species which does not show paramagnetism is .

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  2. Which of the following cannot exist on the basic of MO theory ? .

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  3. Which one paramagnetic and has a bond order of 0.5 ? .

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  4. The bond energies NO,NO^(+) and NO^(Theta) ion follows the order

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  5. In the MO diagram for O(2)^(Theta) ion the highest occupied orbital is...

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  6. Which of the following is not diamagnetic ? .

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  7. The bond order of CO and NO is .

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  8. Combination of two AO s lead to the formation of .

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  9. The possible molecular orbital formed when two d-orbitals overlap is .

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  10. Which of the following species exhibits the diamagnetic behaviour?

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  11. Which of the following species is paramagnetic ? .

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  12. The bond order in NO is 2.5 while that in NO^(o+) is 3 Which of the fo...

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  13. When two AO s combine energy of bonding MO is lowered by x while of an...

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  14. In Which of the following the double bond consist of the pi bonds .

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  15. Which of the following MOs has more than one nodal plane?

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  16. Which of the following MO's has zero nodal planes ? .

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  17. The main axis of diatomic molecule is z. The orbitals px and py overla...

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  18. The paramagnetic property of the oxygen molecule is due to the presenc...

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  19. Which of the following combination is not allowed in the LCAO method f...

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  20. The energy of sigma(2s), is greater than that of sigma(1s)^** orbital ...

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